A minimum-time reorientation of an axisymmetric rigid spacecraft controlled by three torques is studied. The orientation of the body is modeled such that the attitude kinematics are representative of a spin-stabilized spacecraft. The optimal control problem considered is shown to have a switching control structure. Moreover, under certain assumptions, the solutions contain segments that lie on a singular arc. A numerical optimization study is performed using a recently developed method that is designed to accurately solve bang-bang and singular optimal control problems. The optimality conditions for the resulting optimal control problem are derived and analyzed for a variety of cases. Also, the results obtained in this study are compared to a previous method existing in the literature. The key features of the optimized trajectories and controls are identified, and the aforementioned method for solving bangbang and singular optimal control problems is shown to efficiently and accurately solve the problem under consideration.