NH2-MIL-125 Nanosheets Prepared via Crystallization Kinetics Modulation for Ultrathin Membrane Fabrication
Yanwei Sun,
Jiahui Yan,
Mingming Wu
et al.
Abstract:Regulating both crystallographic orientation and thickness of titanium metal−organic framework (Ti-MOF) membranes remains a significant challenge. In this study, we pioneered the fabrication of uniform 29 nm thick NH 2 -MIL-125 nanosheet seeds by employing crystallization kinetics modulation approach. Through innovating confined counter-diffusion-assisted epitaxial growth under single-mode microwave heating, a highly c-oriented 80 nm thick NH 2 -MIL-125 membrane was prepared. Significant reduction in thickness… Show more
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