NH3BH3/LiBH4·NH3 modified by metal hydrides for advanced dehydrogenation

Progress in modification and thermodynamic tuning of light hydrogen storage materials

“…另外, 孙立贤等 [92] 将Ni基MOFs材料与NH 3 BH 3 复合, 王萍等 [93] 通过将NH 3 BH 3 与LiBH 4 和LiNH 2 球磨得到三 元复合体系, 余学斌等 [94] (mol metal min)), 体系的反应活化能仅为19.9 kJ/mol, 图6 为Rh-3D-2D的形貌与特征.…”

Prediction of ternary superconducting YCH12 using a novel solid hydrogen source under high pressure

“…However, these solid hydrogen sources have disadvantages such as a slow dehydrogenation rate, high thermodynamic stability and safety issues. [30][31][32] For example, the utilization of aminoborane can generally release volatile and detrimental ammonia (NH 3 ), borazine (B 3 H 6 N 3 ) and diborane (B 2 H 6 ). 32 The leakage of liquid paraffin is troublesome due to its low melting point.…”

“…[30][31][32] For example, the utilization of aminoborane can generally release volatile and detrimental ammonia (NH 3 ), borazine (B 3 H 6 N 3 ) and diborane (B 2 H 6 ). 32 The leakage of liquid paraffin is troublesome due to its low melting point. 33,34 Besides, most of the synthetic processes are performed under a Laboratory of High Pressure Physics and Material Science (HPPMS), School of high-temperature conditions, where the stress induced by a large temperature difference is liable to damage the DAC, for example 2250 K for YH 9 , 23 1500 K for LaH x 26 and 2000 K for the S-H system.…”

Additives in protic–hydridic hydrogen storage compounds: a molecular study

“…Moreover, mixing light metal hydrides are reported to be very effective to improve their dehydrogenation properties. 36 So here we would like to study whether alkali metal doping with different additives can play a major role in increasing their gravimetric density as well as their dehydrogenation properties. For this, such a combination of ligands are chosen where the ratio of protic and hydridic hydrogen changes.…”