Chem. Commun.
 2023
DOI: 10.1039/d3cc04765b
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NHC-catalyzed radical acylation of cycloalkyl silyl peroxides to access 1,6-,1,7-, and 1,8-diketones

Chaolei Liu,
Jingyi Wang,
Xinlong Liu
et al.

Abstract: An NHC organocatalytic radical acylation of cycloalkyl silyl peroxides with aldehydes was developed for the efficient and rapid synthesis of long-chain 1,6-/1,7-/1,8-diketones, especially unsymmetrical ones.

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