“…1 Battery-type electrode materials rely on strong Faraday reactions to store charges, 2 while capacitive electrode materials are based on three charge storage mechanisms: surface-controlled electric double layer capacitance (EDLC), surface-controlled redox pseudocapacitance and diffusion-controlled intercalation pseudocapacitance. 3 Battery-supercapacitor hybrid (BSH) devices as a type of asymmetric supercapacitors, are typically composed of a high-capacity battery-type electrode such as LiMn 2 O 4 , 4 Bi 2 O 3 , [5][6][7][8] Fe 3 O 4 , 9 Ni 12 P 5 , 10 Ni-Co, 11 Fe 3 C, 12 BiFeO 3 , 13 Bi 2 MoO 6 , 14 and a high-rate capacitive electrode such as carbon nanomaterials, [15][16][17] conducting polymers, 17,18 Nb 2 O 5 , 19 MoS 2 , 20 MXenes, 21 LaMnO 3 . 22 BSH devices emerge as the promising highly-efficient energy storage devices with both high energy density and power density, but usually suffer from the serious mismatch of electrochemical kinetics for cathodes and anodes, mainly due to complex Faradic reactions of the unmatched battery-type electrodes for charge storage, which inevitably degrade rate capability and power density.…”