The carbon fiber (CF) reinforced epoxy composites possess exceptional and distinctive properties as advanced composite materials. However, the flammability of epoxy resin and inadequate interfacial bonding between the resin and CF often impose limitations on their broader application. Herein, in order to enhance the flame retardancy of EP composites effectively, a hierarchical reinforcement was developed by facilely growing MnO2 nanosheets onto CF surface through an in situ process. Owing to their synergistic effects of physical barrier and chemical catalytic behavior, the presence of MnO2 nanosheets can effectively retard the combustion process by facilitating charring formation and suppressing heat and smoke release. Specifically, compared to the Untreated CF, the modified fiber reinforced composites exhibited significantly improved fire safety with reduction of 76.23%, 51.5% and 23.1% in peak heat release rate, total heat release and peak smoke production rate, respectively. Additionally, incorporating MnO2 nanosheets significantly enhanced mechanical properties of the composites, leading to remarkable enhancements of 41.8% in flexural strength and 28.14% in interlaminar shear strength. This study proposes an effective strategy for achieving outstanding flame retardancy and mechanical performance, thereby introducing an innovative concept for the production of high‐performance CF reinforced polymer composites.Highlights
Growth of MnO2 nanoparticles enhanced the mechanical properties of the CF/EP composites.
The CF‐MnO2/EP composites showed excellent flame retardancy.
The flame retardant mechanism of CF‐MnO2/EP composites were analyzed.
Highlight the potential application of MnO2 in the field of flame retardancy.