Nickel and cobalt Co-substituted spinel ZnMn2O4@N-rGO for increased capacity and stability as a cathode material for rechargeable aqueous zinc-ion battery

Tao, Yayuan; Li, Zhi; Tang, Linbin; Pu, Xiaoming; Cao, Tong; Cheng, DingXin; Xu, Qing; Liu, Haimei; Wang, Yonggang; Xia, Yongyao

doi:10.1016/j.electacta.2019.135296

Cited by 96 publications

(60 citation statements)

References 49 publications

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Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

“…Tao et al synthesized Co and Ni co‐substituted ZnMn 2 O 4 nanoparticles to be used as ZIB cathodes. [ 75 ] Results showed that Co and Ni were incorporated into the octahedral sites in replacement of Mn in ZnMn 2 O 4 . This substitution led to larger lattice parameters which could facilitate the Zn 2+ diffusion, and it could also stabilize the spinel structure of the material by inhibiting the Jahn–Teller distortion of Mn 3+ (Figure 6b).…”

Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

“…[ 87 ] Tao et al synthesized Ni and Co co‐substituted spinel ZnMn 2 O 4 nanoparticles through a facile hydrothermal process. [ 75 ] Similarly, Sun et al prepared Ca 2+ and water stabilized Ca 0.28 MnO 2 ·0.5H 2 O using a simple one step hydrothermal method. [ 85 ] Recently, Ce‐doped MnO 2 nanorod was fabricated though a one‐step hydrothermal route and applied as ZIBs cathode.…”

Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

“…Tao et al reported Ni and Co co‐substituted spinel ZnMn 2 O 4 as a cathode for ZIBs with good stability. [ 75 ] Ni and Co co‐substituting could stabilize spinel ZnMn 2 O 4 crystal for Zn 2+ insertion and extraction without volume expansion, which led to an excellent cycle performance. The lattice spacing could be enlarged when Ni and Co ions co‐substituted half of Mn ions in ZnMn 2 O 4 which decreased the hindrance for zinc insertion/extraction.…”

Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

See 3 more Smart Citations

Defect Engineering in Manganese‐Based Oxides for Aqueous Rechargeable Zinc‐Ion Batteries: A Review

Xiong

Zhang

Lee

et al. 2020

Advanced Energy Materials

313

150

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The development of advanced cathode materials for aqueous the zinc ion battery (ZIB) represents a crucial step toward building future large‐scale green energy conversion and storage systems. Recently, significant progress has been achieved in the development of manganese‐based oxides for ZIB via defect engineering, whereby the intrinsic capacity and energy density have been enhanced. In this review, an overview of the recent progress in the defect engineering of manganese‐based oxides for aqueous ZIBs is summarized in the following order: 1) the structures and properties of the commonly used manganese‐based oxides, 2) the classification of the various types of defect engineering commonly reported, 3) the various strategies used to create defects in materials, and 4) the effects of the various types of defect engineering on the electrochemical performance of manganese‐based oxides. Finally, a perspective on the defect engineering of manganese‐based oxides is proposed to further enhance their electrochemical performance as a ZIB cathode.

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Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

Section: Defect Engineering On Manganese‐based Oxidesmentioning

confidence: 99%

See 2 more Smart Citations

Defect Engineering in Manganese‐Based Oxides for Aqueous Rechargeable Zinc‐Ion Batteries: A Review

Xiong

Zhang

Lee

et al. 2020

Advanced Energy Materials

313

150

View full text Add to dashboard Cite

show abstract

“…Manganate is an important component of manganese-based materials. Some manganates are investigated as cathode materials for AZIBs, such as LiMn 2 O 4 (Wu et al, 2015), ZnMn 2 O 4 (Zhang et al, 2016;Wu et al, 2017;Chen et al, 2019c), KMn 8 O 16 (Cui et al, 2018), and their derivatives (Tao et al, 2020).…”

Section: Manganatementioning

confidence: 99%

Application of Manganese-Based Materials in Aqueous Rechargeable Zinc-Ion Batteries

et al. 2020

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In recent years, aqueous rechargeable zinc-ion batteries (AZIBs) have attracted more and more attention not only because they use earth-abundant metals but also due to their improved safety and high volumetric energy density. As one type of promising electrode material for AZIBs, manganese-based materials are receiving considerable attention owing to their high theoretical specific capacity, non-toxicity, and low cost. This mini review summarizes the recent advances on the application of manganesebased materials (manganese oxide, manganate, and their composites) in AZIBs. In addition, the methods to enhance their zinc-ion storage properties are summarized and discussed, such as morphology engineering, doping, as well as compositing with other materials. Ultimately, some personal prospects for future research of the manganese-based materials for AZIBs are also proposed.

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Intrinsic Structure Modification of Electrode Materials for Aqueous Metal‐Ion and Metal‐Air Batteries

Ling

Wang

Chen

et al. 2020

Adv Funct Materials

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In consideration of low cost, simple operation, safe reliability, and environmental benignity, aqueous rechargeable batteries (ARBs) have attracted great interest among portable electronic devices, energy storage, and power source batteries. As the key components of ARBs, the electrode materials lead to a crucial effect for the overall battery properties, such as working voltage, electrocatalytic activity, capacity, and cycling stability. However, owing to the highly reactive aqueous environment, the electrode materials typically demonstrate a series of issues, including active material dissolution, structural instability, and poor catalytic activity, restricting their application. So far, several researchers have devoted much effort to improve the properties of electrode materials for ARBs. In particular, intrinsic structure modification in terms of vacancy regulation, interlayer engineering, and element doping have been applied to optimize the electronic and phase structure of electrode materials, contributing to elevated ion diffusion, fast charge transfer, and adequate active sites for electrochemical reaction. In this review, recent reports are demonstrated about the intrinsic structure modification of electrode materials in aqueous metal‐ion and metal‐air batteries, focusing on various regulation strategies and functional mechanisms. Finally, a brief conclusion and perspective is presented to demonstrate constructive suggestions and opinions for further research.

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Nickel and cobalt Co-substituted spinel ZnMn2O4@N-rGO for increased capacity and stability as a cathode material for rechargeable aqueous zinc-ion battery

Cited by 96 publications

References 49 publications

Defect Engineering in Manganese‐Based Oxides for Aqueous Rechargeable Zinc‐Ion Batteries: A Review

Defect Engineering in Manganese‐Based Oxides for Aqueous Rechargeable Zinc‐Ion Batteries: A Review

Application of Manganese-Based Materials in Aqueous Rechargeable Zinc-Ion Batteries

Intrinsic Structure Modification of Electrode Materials for Aqueous Metal‐Ion and Metal‐Air Batteries

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