Nickel-catalyzed arylcyanation of alkenes via cyano group translocation: access to 1,n-dinitriles or 4-amino nitriles

Li, Xiaohong; Wang, Shenfan; Fu, Xiangxiang; Xing, Donghui; Fu, Zeyuan; Deng, Yuanfu; Jiang, Huanfeng; Huang, Liangbin

doi:10.1007/s11426-024-2006-1

Sci. China Chem.

2024

DOI: 10.1007/s11426-024-2006-1

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Nickel-catalyzed arylcyanation of alkenes via cyano group translocation: access to 1,n-dinitriles or 4-amino nitriles

Xiaohong Li,

Shenfan Wang,

Xiangxiang Fu

et al.

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2024

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Synthesis of Tetrasubstituted Alkenes by Rhodium-Catalyzed Regioselective Cyano Transfer

Chang,

Guo,

Zhong

et al. 2024

Org. Lett.

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We describe herein a novel, general, and robust approach to structurally diversified alkenyl nitriles through a Rhcatalyzed cyano transfer reaction between alkynyl-malononitrile derivatives and aryl/alkenyl boronic acids. This reaction exhibits high chemo-and regioselectivity and a broad substrate scope. The tetrasubstituted alkenyl dinitriles (34 examples, average 58% yield) are obtained through substrate tuning and ligand control.

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Synthesis of Tetrasubstituted Alkenes by Rhodium-Catalyzed Regioselective Cyano Transfer

Chang,

Guo,

Zhong

et al. 2024

Org. Lett.

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show abstract

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Nickel-catalyzed arylcyanation of alkenes via cyano group translocation: access to 1,n-dinitriles or 4-amino nitriles

Cited by 1 publication

References 81 publications

Synthesis of Tetrasubstituted Alkenes by Rhodium-Catalyzed Regioselective Cyano Transfer

Synthesis of Tetrasubstituted Alkenes by Rhodium-Catalyzed Regioselective Cyano Transfer

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