Nickel-Catalyzed Heck Reaction

Mittal, Kavita; Gahlot, Pragya

doi:10.1055/s-0042-1751432

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Applications Of Tbhp In Heterocyclic Ring Formations1

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2024

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“…A thorough analysis of several synthetic methodologies that produced (CC), (CN), and (CS) bonds utilizing the I 2 /TBHP reagent system was compiled by Kapoor et al between 2010 and 2021 [14]. In keeping with our interest in investigating the uses of redox reagents [15–24], as of right now, there is not a thorough and critical evaluation of the literature on the applications of TBHP in heterocyclic ring formations. In this update, we discuss the most notable contributions of TBHP that have documented the scope of the reaction and provided mechanistic insights in heterocyclic ring formations from 2018 to date.…”

Section: Applications Of Tbhp In Heterocyclic Ring Formationsmentioning

confidence: 99%

Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Varala,

Seema,

Amanullah

et al. 2024

Journal of Heterocyclic Chem

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One of the most often utilized hydroperoxides in an array of oxidation strategies is tert‐butyl hydroperoxide (tBuOOH, TBHP). The key reasons for rising utility of TBHP are its low cost, environmental friendliness, high efficiency, and ability to replace hazardous or rare heavy metal oxidants. In this sexennial update, we concisely and critically discussed the applications of TBHP in heterocyclic ring formations starting from 2018 to date. Merits and demerits of its utility, scope of a synthetic organic transformation along with mechanistic logistics are the key features of this review.

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Section: Applications Of Tbhp In Heterocyclic Ring Formationsmentioning

confidence: 99%