Nickel‐Catalyzed Hydroborylative Polycyclization of Allenynes: an Atom‐Economical and Diastereoselective Synthesis of Bicyclic 5–5 Fused Rings.

Abstract

It‘s a kind of magic: Ni catalyzes the formation of two C−C and one C−B bonds to afford boronate‐containing bicycles in a fully atom‐economical process. Details can be found in the Research Article by Diego J. Cárdenas, M. Teresa Quirós and co‐workers (I. Manjón‐Mata, M. T. Quirós, E. Velasco‐Juárez, E. Buñuel, D. J. Cárdenas, Adv. Synth. Catal. 2022, 364, 1616–1723; DOI: 10.1002/adsc.202101462).