Nickel Complexes with Carbonyl, Isocyanide, and Carbene Ligands

Kubiak, Clifford P.

doi:10.1016/b978-008046519-7.00076-9

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Iiia4 Reactivity Of Ni(0) Metallocyclynes With Small Molecules1

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1999

2021

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Cited by 5 publications

(1 citation statement)

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“…Nickel metal on exposure to CO forms Ni(CO) 4 97 and is the only metal to react appreciably with CO at standard temperature and pressure. 98 In fact, exposure to CO is one way nickel catalysts are removed from reaction mixtures, 99 and nickel metal is purified. 100 Exposure of allyl and 1,3-butadiene complexes of Ni(0) to CO gives Ni(CO) 4 and dimerized and trimerized ligand coupling products.…”

Section: Iiia4 Reactivity Of Ni(0) Metallocyclynes With Small Moleculesmentioning

confidence: 99%

ortho-Arene Cyclynes, Related Heterocyclynes, and Their Metal Chemistry

1999

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Section: Iiia4 Reactivity Of Ni(0) Metallocyclynes With Small Moleculesmentioning

confidence: 99%

ortho-Arene Cyclynes, Related Heterocyclynes, and Their Metal Chemistry

1999

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Nickel‐Catalyzed Carbonylations

Das

Bhanage

2021

Carbon Monoxide in Organic Synthesis

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Nickel(0)‐Mediated [3+2+2] and [2+2+2+1] Cyclization Reactions of Chromium Fischer Carbene Complexes and Alkynes

et al. 2003

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[Ni(cod)2] ändert die Reaktivität von Fischer‐Carben‐Komplexen drastisch: Statt nach einer Dötz‐[3+2+1]‐Benzanellierung substituierte Phenole zu ergeben, reagieren Chrom‐Alkenylcarben‐Komplexe mit zwei Äquivalenten Alkin nach einer [3+2+2]‐Cyclisierung, einfache Carbenkomplexe nach einer [2+2+2+1]‐Cyclisierung (siehe Schema; cod=1,5‐Cyclooctadien). Beide Reaktionen sind regio‐ und diastereoselektiv.

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Nickel Complexes with Carbonyl, Isocyanide, and Carbene Ligands

Cited by 5 publications

References 188 publications

ortho-Arene Cyclynes, Related Heterocyclynes, and Their Metal Chemistry

ortho-Arene Cyclynes, Related Heterocyclynes, and Their Metal Chemistry

Nickel‐Catalyzed Carbonylations

Nickel(0)‐Mediated [3+2+2] and [2+2+2+1] Cyclization Reactions of Chromium Fischer Carbene Complexes and Alkynes

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