Nickel(II) Peroxide

Morrow, Gary W.

doi:10.1002/047084289x.rn017

Cited by 1 publication

(2 citation statements)

References 22 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The production of these derivatives is a common consequence of exposing Ni complexes to these particular conditions. − Although exposure to WOR conditions often destabilizes a lot of Ni compounds, it is worth noting that the stable phase of many of these compounds under the WOR conditions is typically Ni (hydr)oxide. − This means that despite the challenges presented by the WOR conditions, only this specific form of Ni maintains stability. Ni(III) (hydr)oxide is a potent oxidizing agent for many organic compounds. It demonstrates significant reactivity and serves as a powerful oxidant when it comes to the oxidation of a wide range of such compounds. ,− …”

Section: Resultsmentioning

confidence: 99%

See 1 more Smart Citation

Exploring an Electrochemical Route for Water-Enhanced Oxygenation Reactions Utilizing Nickel Molecular Structures: A Case Study

Behrouzi,

Mohammadi,

Dau

et al. 2024

Inorg. Chem.

View full text Add to dashboard Cite

Recently, Ni molecular catalysis has been extensively applied in oxygenation reactions. This work is underpinned by the characterization techniques and the discovered instability of the Ni-bipyridine/phenanthroline system, which results in Ni (hydr)oxide production under oxidative conditions. The practical applications of this mechanism by employing a prepared Ni (hydr)oxide-based electrode specifically in the oxygenation of sulfides, achieving noteworthy yields in contrast to noncatalyst control experiments, are explored. Thus, a Ni (hydr)oxide-based material is proposed as a candidate for the true catalyst for sulfide oxidation in the presence of the Ni-bipyridine/phenanthroline system. The findings of this study are expected to stimulate discussion and encourage new viewpoints within the chemical community regarding the potential applications and mechanisms of molecular catalysts in oxidation reactions.

show abstract

Section: Resultsmentioning

confidence: 99%

“…Ni(III) (hydr)oxide is a potent oxidizing agent for many organic compounds. It demonstrates significant reactivity and serves as a powerful oxidant when it comes to the oxidation of a wide range of such compounds. ,− …”

Section: Resultsmentioning

confidence: 99%