2021
DOI: 10.1016/j.isci.2020.101920
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Nitrogen-doped nanoporous graphene induced by a multiple confinement strategy for membrane separation of rare earth

Abstract: Summary Rare earth separation is still a major challenge in membrane science. Nitrogen-doped nanoporous graphene (NDNG) is a promising material for membrane separation, but it has not yet been tested for rare earth separation, and it is limited by multi-complex synthesis. Herein, we developed a one-step, facile, and scalable approach to synthesize NDNG with tunable pore size and controlled nitrogen content using confinement combustion. Nanoporous hydrotalcite from Zn(NO 3 ) … Show more

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Cited by 35 publications
(21 citation statements)
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“…However, the limitation of interlayer spacing in GO membranes leads to low ion penetration. In order to solve this problem, Tan et al used confinement combustion to synthesize nitrogen-doped nanoporous graphene (NDNG) with adjustable pore size and controlled nitrogen content 1555 . The NDNG membranes exhibit good separation selectivity (~3.7) for Sc 3+ from other rare-earth ions and ~1.7 for Tm 3+ /Sm 3+ .…”
Section: Carbon Neutralization and Exhaust Gas Treatmentmentioning
confidence: 99%
“…However, the limitation of interlayer spacing in GO membranes leads to low ion penetration. In order to solve this problem, Tan et al used confinement combustion to synthesize nitrogen-doped nanoporous graphene (NDNG) with adjustable pore size and controlled nitrogen content 1555 . The NDNG membranes exhibit good separation selectivity (~3.7) for Sc 3+ from other rare-earth ions and ~1.7 for Tm 3+ /Sm 3+ .…”
Section: Carbon Neutralization and Exhaust Gas Treatmentmentioning
confidence: 99%
“…X-ray diffraction (XRD) of PGQD didn't show the typical broad (002) peak (Figure 4b), which could be attributed to the large amount of PEG coating on the surface of GQD. However, the strong D peak (1386 cm -1 ) and G peak (1599 cm -1 ) could be found in Raman spectra (Figure S3) of PGQD, which confirmed the feature structure [38][39][40]. As compared with the Fourier transform infrared (FTIR) spectrum of GO, the strong and broad absorption peak at ≈3400 cm -1 from the O-H stretching vibration could be observed in PGQD and PEG [41].…”
Section: Synthesis and Characterizations Of Pgqdmentioning
confidence: 56%
“…The nanopores of graphene membranes provide a significant pathway for ion penetration, therefore the ion selectivity facilitates the metal ion separation, Furthermore, the ion diffusion of porous graphene membranes can be enhanced by acid addition. To develop a metal ion separation performance, the pores of a graphene membrane can be modified by using oxide functional group derivatives [ 78 , 79 , 80 ]. The membrane modules often used in separation of mercury and heavy metals are hollow fibers and sheet layers [ 71 , 81 , 82 ].…”
Section: Membrane Separation For Mercury and Heavy Metalsmentioning
confidence: 99%