Nitroxide Radicals as Templating Agents in the Synthesis of Magnets Based on Three-Dimensional Oxalato-Bridged Heterodimetallic Networks

Ballester, Gloria; Coronado, Eugenio; Giménez‐Saiz, Carlos; Romero, Francisco Martín

doi:10.1002/1521-3773(20010216)40:4<792::aid-anie7920>3.3.co;2-c

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“…In supramolecular assemblies of radical cations with other anions, open shell anions will have magnetic interactions with radical cations in the absence of chemical bonds through space, and even the close shell anions will also influence the magnetic interactions between the adjacent radical cations in the system. Such compounds are good examples for the study of magnetic interactions through space [3][4][5][6][7][8][9][10][11][12][13][14][15].…”

Section: Introductionmentioning

confidence: 96%

Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)₂]⁻ anions

Zhou

Chen

et al. 2009

Journal of Coordination Chemistry

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2009) Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN) 2 ] − anions, Journal of Coordination Chemistry, 62:24, 3913-3920,,5,5-tetramethyl-4,5-dihydro-1H-imidazo-1-oxyl-3-oxide radical cation) has been synthesized from the combination of p-N-methylpyridinium nitronyl nitroxide radical cations and [Au(CN) 2 ] À anions, and characterized structurally as well as magnetically. The compound crystallizes in the orthorhombic, space group P2 1 2 1 2 1 , with two independent p-MePyNN þ cations separated from each other by the dimer ½AuðCNÞ À 2 2 . The magnetic study shows that the larger steric hindrance of [Au(CN) 2 ] À anion influences the magnetic interactions between the radical cations, with very weak antiferromagnetic interactions.

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Section: Introductionmentioning

confidence: 96%

Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)₂]⁻ anions

Zhou

Chen

et al. 2009

Journal of Coordination Chemistry

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show abstract

Nitroxide Radicals as Templating Agents in the Synthesis of Magnets Based on Three-Dimensional Oxalato-Bridged Heterodimetallic Networks

Cited by 1 publication

References 1 publication

Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)₂]⁻ anions

Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)₂]⁻ anions

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Nitroxide Radicals as Templating Agents in the Synthesis of Magnets Based on Three-Dimensional Oxalato-Bridged Heterodimetallic Networks

Cited by 1 publication

References 1 publication

Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)2]− anions

Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)2]− anions

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Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)₂]⁻ anions

Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical cations and [Au(CN)₂]⁻ anions