Water saturation is the most significant characteristic for reservoir characterization in order to assess oil reserves; this paper reviewed the concepts and applications of both classic and new approaches to determine water saturation. so, this work guides the reader to realize and distinguish between various strategies to obtain an appropriate water saturation value from electrical logging in both resistivity and dielectric has been studied, and the most well-known models in clean and shaly formation have been demonstrated. The Nuclear Magnetic Resonance in conventional and nonconventional reservoirs has been reviewed and understood as the major feature of this approach to estimate Water Saturation based on T2 distribution. Artificial intelligence has recently been used to predict water saturation and other parameters in the reservoir characterization process using seismic data, so the main idea of this technique and a list of the author's researchers have been reviewed. In this review article, the reference approach using core analysis by distillation-extraction and retorting techniques have been explained, as well as the saturation-height method, which is based on the capillary pressure concept and wettability. Finally, alternative experimental approaches based on scanning are expressed in this manner.