NMR investigation of platinum–diphosphine complexes in [BMIM][PF6] ionic liquid

Reaction Rates as a Function of Scale within Ionic Liquids: Microscale in Droplet Microreactors versus Macroscale Reactions in the Case of the Grieco Three‐Component Condensation Reaction

“…Another explanation could be that the polymerisation of indene acts as a competitive reaction catalysed by the Lewis acid BF 3 , [40] generated during the hydrolysis of the BF 4 À ion. At the microscopic scale (Figure 2), the reaction kinetics and the conversion rates appear similar in À hydrolysis might occur as well, as reported in the literature, [41,42] favoured by a high surface/ volume ratio in the droplet format. The F À ions generated from the PF 6 À can perturb the reaction, following the same processes as for BF 4 À .…”

“…[46] what has been observed in the macroscopic scale, the reaction is much slower in the microscopic format in [bmim]- 6 ] as solvent. PF 6 À hydrolysis might occur as well, as reported in the literature, [41,42] favoured by a high surface/ volume ratio in the droplet format. The F À ions generated from the PF 6 À can perturb the reaction, following the same processes as for BF 4 À .…”

Magnetic resonance spectroscopy in ionic liquids

“…Kollár et al have investigated the formation of platinum-diphosphine complexes in [bmim]PF 6 by 31 P NMR spectroscopy [121]. The insertion reaction of SnCl 2 into the Pt-Cl bond of PtCl 2 (bdpp) was observed by the formation of corresponding resonances in the 31 P spectra.…”

Activation of Small Molecules by P-Ligand—Platinum Metal Complexes in Ionic Liquids

“…PtCl(SnCl 3 ) (bdpp), Pt(SnCl 3 ) 2 (bdpp) and [Pt(bdpp)(PPh 3 )Cl] + complexes (where bdpp = 2,4-bis(diphenylphosphino)pentane) were identified in the reaction of PtCl 2 (bdpp) with tin(II)chloride and PPh 3 , respectively [45].…”