NMR of Metal Nuclides. Part I. the Main Group Metals

Dechter, James J.

doi:10.1002/9780470166307.ch5

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Organylboranes and Miscellaneous Compounds1

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2017

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Cited by 33 publications

(1 citation statement)

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“…However, the d 11 B values of iminoboranes, R-BN-R 0 , fall in the range of 3-22 ppm and are sensitive to the nature of the substituents at the site of the imino nitrogen atom. By contrast, another triorganylborane compound, 7-borabicyclo[2.2.1]heptadiene ( [2], d-5 ppm), exhibits a significant upfield shift, and the magnitude of this shift is rationalized in terms of the interaction of the empty p orbital on boron with the p-clouds of two C]C bonds. 11 B chemical shifts have proved to be an extremely valuable tool for distinguishing between three-and four-coordinate boron compounds.…”

Section: Organylboranes and Miscellaneous Compoundsmentioning

confidence: 98%

NMR Spectroscopy, Heteronuclei, B, Al, Ga, In, Tl

Lewiński

Kubicki²

2017

Encyclopedia of Spectroscopy and Spectrometry

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Section: Organylboranes and Miscellaneous Compoundsmentioning

confidence: 98%

NMR Spectroscopy, Heteronuclei, B, Al, Ga, In, Tl

Lewiński

Kubicki²

2017

Encyclopedia of Spectroscopy and Spectrometry

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Alkali Metals: Inorganic ChemistryBased in part on the article Alkali Metals: Inorganic Chemistry by Francis S. Mair & Ronald Snaith which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Leung

2005

Encyclopedia of Inorganic Chemistry

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This article is updated to cover the literature in the area of inorganic chemistry of alkali metals since 1993. The advancement in instrumentation and spectroscopic techniques in the past decade has provided the researchers with more powerful tools for structure determination of compounds. In this respect, alkalides containing mixed‐sandwich complexes of alkali metal cations, complexes with dimers or chains of alkali metal anions, electrides with alkali metal ions intercalating in zeolite, and interstitial hydride enclosed by an unusual (Li + ) 8 cubic cage have been found or studied by NMR. With the successful preparation of Na 3 N recently, its correct structure has been revealed. The exact composition of ‘NaB 6 ’ has also been determined. The role of alkali metals in trielide clusters of traditional Zintl polyanions has been demonstrated. Trimetallic Li‐Na‐K amides, alkoxide compounds, and highly aggregated cage structures of lithium‐heavier alkali metal alkoxides have been reported.

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Electrolytes

Holz¹

2007

Encyclopedia of Magnetic Resonance

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NMR of Metal Nuclides. Part I. the Main Group Metals

Cited by 33 publications

References 279 publications

NMR Spectroscopy, Heteronuclei, B, Al, Ga, In, Tl

NMR Spectroscopy, Heteronuclei, B, Al, Ga, In, Tl

Alkali Metals: Inorganic ChemistryBased in part on the article Alkali Metals: Inorganic Chemistry by Francis S. Mair & Ronald Snaith which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Electrolytes

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