2008
DOI: 10.1016/j.carres.2008.04.012
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NMR spectroscopic analysis of exopolysaccharides produced by Leuconostoc citreum and Weissella confusa

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Cited by 177 publications
(116 citation statements)
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“…3D). The 1 H correlations among different proton signals and their relatively large coupling constant of about 10 Hz (52), as well as the 1 H spectrum and its chemical shifts (Table 4), suggest a dextran-type carbohydrate configuration based on ␣-(1¡6)-linked D-glucopyranosyl units (35). Finally, a number of signals in proton spectra (Fig.…”
Section: Resultsmentioning
confidence: 97%
See 1 more Smart Citation
“…3D). The 1 H correlations among different proton signals and their relatively large coupling constant of about 10 Hz (52), as well as the 1 H spectrum and its chemical shifts (Table 4), suggest a dextran-type carbohydrate configuration based on ␣-(1¡6)-linked D-glucopyranosyl units (35). Finally, a number of signals in proton spectra (Fig.…”
Section: Resultsmentioning
confidence: 97%
“…Lactic acid bacteria (LAB) can produce a large structural variety of EPS and oligosaccharides from glucose that differing in size, molecular organization, chemical composition, structure, and genetic determinants (41) through the activity of glycansucrase and glycosyltransferase (GTF) enzymes. The chemical composition of repeating units of EPS produced by microorganisms has been determined by nuclear magnetic resonance (NMR) spectroscopy (31,35,48,51) through the application of 1 H and 13 C NMR mono-and bidimensional spectra (19). An updated review of composition, structure, and yield of homopolysaccharides (HoPS) and heteropolysaccharides (HePS) synthesized by LAB strains determined by NMR spectroscopy was previously reported (50).…”
mentioning
confidence: 99%
“…Data within a column followed by the same letter are not significantly different according to Tukey's test. P value: ***, P b 0.001. , are commonly present in the sourdough ecosystems produced in different countries (Choi et al, 2012;Coppola et al, 1996;De Vuyst et al, 2002;Iacumin et al, 2009;Robert et al, 2006Robert et al, , 2009Valmorri et al, 2006) and might also contribute to the structure of the final dough by exopolysaccharides (Choi et al, 2012;Di Cagno et al, 2006;Galle et al, 2010;Maina et al, 2008). Specifically, the strains Lb.…”
Section: Discussionmentioning
confidence: 99%
“…The peak at 4.92 ppm is due to the H-1 of the (1-6) glucosyl residues of main chain (Bounaix et al, 2009;Kanimozhi et al, 2017).The two signals that appear centered at 5.25 and 5.26 ppm represent important structural characteristics of -(1,3)-linked-dglucosyl residues (Maina et al, 2008;Bounaix et al, 2009) 1 H NMR spectra confirmed the presence of a large percentage of -(1-6) linear linkages with very few -(1-3) branch points in the structure of L. lactis produced dextran. In a previous study, the -1,6-glycosidic linkage in the main chains was demonstrated at a peak of 4.93 ppm, whereas -1, 3-glycosidic link-age in the branch is located at approximately 5.20 ppm (Gan et al, 2014).…”
Section: H Nmrmentioning
confidence: 99%