NMR study of Al(III) complexation and solvation in alcohol and water-alcohol solutions

Kon'shin, V. V.; Chernyshov, B. N.

doi:10.1007/bf00748129

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“…Because Al(OTf)3 can act as a strong L acid site during GLY conversion, it was assumed that the aluminum cation preferentially coordinated with the hydroxyl group. 1 H NMR examinations can detect complex formation and have been used to investigate the complexation between metal sites and inactivated alcohols [44,45]. Thus, we carried out 1 H NMR studies on the complexation of Al(OTf)3 to GLY to determine whether the aluminum cation coordinated with both the hydroxyl oxygen atoms.…”

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confidence: 99%