2024
DOI: 10.1002/ange.202410759
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Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

Huan Luo,
Junzhi Liu

Abstract: Introduction of nonhexagons and/or heteroatoms allows for finely tuning the physicochemical properties of nanographenes. Heteroatoms doping have dominated the modulation of nanographenes with tunable bandgap, rich electrochemical activities and so on. The pair of nonhexagons, for instance, pentagon‐heptagon pairs, have furnished nanographenes with aromatic and/or antiaromatic characteristics, open‐shell properties and so on. In order to meet the growing demand for versatile nanographenes in materials science, … Show more

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