Non-classical hydrogen bond (CH∙∙∙I) directed self-assembly formation of a novel 1D supramolecular polymer, based on a copper complex [Cu{(CH3)2SO}6]I4

Garzón-Tovar, Luis; Duarte-Ruiz, Álvaro; Wurst, Klaus

doi:10.1016/j.inoche.2013.03.024

Cited by 22 publications

(8 citation statements)

References 22 publications

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“…This contribution is part of the recent efforts of several groups to synthesize new polyiodide containing hybrid materials and to understand the principles of caging small polyiodide anions [31][32][33][34][36][37][38] and iodine molecules [60][61][62]. The hydrogen bonded framework of 1,8-diaminiumoctane bis(triiodide), (H 3 N-(CH 2 ) 8 -NH 3 )[I 3 ] 2 , is constructed by one-dimensional staircase-shaped motifs which are connected with each other by polyiodide and alkan-diyl units.…”

Section: Discussionmentioning

confidence: 99%

“…The rod-shaped building blocks can be understood as tectons used for the crystal engineering of new functional materials [29,30]. It has been shown, especially for polyiodides, that tailored materials can be constructed, and that their structures fit with the lengths and shapes of the tectons used [31][32][33][34][35][36][37][38][39]. This selective and robust synthetic protocol for solid polyiodides using rod-shaped tectons or templates is now generally termed dimensional caging [31].…”

Section: Open Accessmentioning

confidence: 99%

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I62− Anion Composed of Two Asymmetric Triiodide Moieties: A Competition between Halogen and Hydrogen Bond

Megen

Reiß

2013

Inorganics

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The reaction of 1,8-diaminooctane with hydroiodic acid in the presence of iodine gave a new polyiodide-containing salt: 1,8-diaminiumoctane bis(triiodide), (H 3 N-(CH 2) 8-NH 3)[I 3 ] 2. The title compound has been characterized by crystallographic and spectroscopic methods. The polyiodide ion is the first example of a hydrogen bonded I 6 2− dianion consisting of two very asymmetric triiodide components with I−I distances of 2.7739(4) and 3.1778(4) Å interacting by a weak halogen bond (I•••I: 3.5017(2) Å). The structural parameters of the triiodide anions, derived from X-ray crystallographic data, are in good agreement with the Raman and Far-IR spectroscopic results.

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Section: Discussionmentioning

confidence: 99%

Section: Open Accessmentioning

confidence: 99%

I62− Anion Composed of Two Asymmetric Triiodide Moieties: A Competition between Halogen and Hydrogen Bond

Megen

Reiß

2013

Inorganics

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“…Jang and coworkers reported the use of a neutral tripodal receptor based on a triethylbenzene derivative with 2-aminobenzimidazole moieties 22 for chromogenic and fluorescent recognition of I À in CH 3 CNÀ H 2 O with a limit of 7.45 μM and a fast analytical response. [65] Of note, recent works have include other non-common Hbond donors such as sp 3 or sp 2 -hybridized CÀ H groups [75] or boronic acids B(OH) 2 [71] (Figure 7). Dorazco and coworkers reported the cationic porphyrin 23 is able to detect iodide in pure water at pH = 7.4 [66] with a rapid, direct analytical response and a detection limit of 180 nM.…”

Section: Intermolecular Hydrogen Bondsmentioning

confidence: 99%

“…This enhancement of emission intensity upon iodide binding is particularly notable because it is more common to observe quenching behaviour of emissive organic anion receptors and transition-metal-based receptors. [59,[66][67][73][74][75][76]…”

Section: (Cà I•••i à ) Halogen Bondsmentioning

confidence: 99%

Recent Advances in Luminescent Recognition and Chemosensing of Iodide in Water

Valdes‐García

Rosales‐Vázquez

Bazany‐Rodríguez

et al. 2020

Chemistry An Asian Journal

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This Minireview covers the latest developments of chemosensors based on transition-metal receptors and organic fluorophores with specific binding sites for the luminescent detection and recognition of iodide in aqueous media and real samples. In all selected examples within the last decade (made-post 2010), the iodide sensing and recognition is probed by monitoring real-time changes of the fluorescence or phosphorescence properties of the chemosensors. This review highlights effective strategies to iodide sensing from a structural approach where the iodide recognition/sensing process, through supramolecular interactions as coordination bonds, hydrogen bonds, halogen bonds and electrostatic interactions, is transduced into an optical change easily measurable. The selective iodide sensing is an active field of research with global interest due to the importance of iodide in biological, medicinal, industrial, environmental and chemical processes.

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“…For related structures, see Garzó n-Tovar et al (2013); Long et al (1999); Tkachev et al (1994). For supramolecular polymers formed by non-classical hydrogen bonds, see: Fromm (2001); Huang & Scherman (2012); Youm et al (2006).…”

Section: Related Literaturementioning

confidence: 99%

Hexakis(dimethyl sulfoxide-κO)zinc(II) polyiodide

Garzón-Tovar¹,

Duarte-Ruiz²,

Fanwick³

2013

Acta Cryst E

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The title compound, [Zn{(CH3)2SO}6]I4, is a one-dimensional supramolecular polymer along a threefold rotation axis of the space group. It is built up from discrete [Zn{(CH3)2SO}6]2+ units connected through non-classical hydrogen bonds to linear I4 2− polyiodide anions (C—H⋯I = 3.168 Å). The ZnII ion in the cation has an octahedral coordination geometry, with all six Zn—O bond lengths being equivalent, at 2.111 (4) Å. The linear polyiodide anion contains a neutral I2 molecule weakly coordinated to two iodide ions.

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Non-classical hydrogen bond (CH∙∙∙I) directed self-assembly formation of a novel 1D supramolecular polymer, based on a copper complex [Cu{(CH3)2SO}6]I4

Cited by 22 publications

References 22 publications

I62− Anion Composed of Two Asymmetric Triiodide Moieties: A Competition between Halogen and Hydrogen Bond

I62− Anion Composed of Two Asymmetric Triiodide Moieties: A Competition between Halogen and Hydrogen Bond

Recent Advances in Luminescent Recognition and Chemosensing of Iodide in Water

Hexakis(dimethyl sulfoxide-κO)zinc(II) polyiodide

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