Smart materials based on carbon-fibre-reinforced plastic (CFRP) with embedded PZT sensors and actuators are expected to be a favourite composite for vibration damping and noise reduction. Due to the wide variety of physical properties of the components, various damage mechanisms may reduce or even remove the sensing and actuating capabilities of the piezoceramic material. Comprehensive non-destructive characterization and integral health monitoring help to optimize the structure and its manufacturing and are essential prerequisites to ensure performance and availability of smart components during their lifetime. The first part of the paper presents high-resolution non-destructive imaging methods including microfocus x-rays, ultrasonics and eddy currents. These methods are used to characterize damage resulting from non-optimal manufacturing and external load. The second part is dedicated to newly developed imaging techniques using the active piezoceramics as transmitters of acoustic, electromagnetic and thermal fields. The third part focuses on health monitoring by impedance spectroscopy using the same piezoceramics as for vibration damping. Electromechanical finite-element modelling and experimental investigations of strip-shaped specimens have shown the close connection between mechanical properties and electrical impedance.