Fibre reinforced polymer (FRP) rods are widely used as corrosion-resistant reinforcing in civil structures. However, developing a method to determine the loads on in-service FRP rods remains a challenge. In this study, the entropy of acoustic emission (AE) emanating from FRP rods is used to estimate the applied loads. As loads increased, the fraction of AE hits with higher entropy also increased. High entropy AE hits are defined using the one-sided Chebyshev’s inequality with parameter k = 2 where the histogram of AE entropy up to 10–15% of ultimate load was used as a baseline. According to the one-sided Chebyshev’s inequality, when more than 20% (k = 2) of AE hits that fall further than two standard deviations away from the mean are classified as high entropy events, a new distribution of high entropy AE hits is assumed to exist. We have found that the fraction of high AE hits. In glass FRP and carbon FRP rods, a high entropy AE hit fraction of 20% was exceeded at approximately 40% and 50% of the ultimate load, respectively. This work demonstrates that monitoring high entropy AE hits may provide a useful means to estimate the loads on FRP rods.