2005
DOI: 10.1295/polymj.37.418
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Non-isothermal Crystallization of Poly(ethylene-co-glycidyl methacrylate)/Silica Nanocomposites

Abstract: ABSTRACT:Nano-sized silica particles were modified by -aminopropyltriethoxysilane and the modified and unmodified silica particles were then respectively compounded with poly(ethylene-co-glycidyl methacrylate) (PEGMA) in a twin-screw extruder. Non-isothermal crystallization behaviors of neat PEGMA, PEGMA/unmodified silica (Silica), and PEGMA/modified silica (A-Silica) were studied by differential scanning calorimeter at various cooling rates. Modified Avrami model, Ozawa model, and Liu model all successfully d… Show more

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