Quantum phases of electrons in the filling factor range 2 ≤ ν ≤ 3 are probed by the weak optical emission from the partially populated second Landau level and spin wave measurements. Observations of optical emission include a multiplet of sharp peaks that exhibit a strong filling factor dependence. Spin wave measurements by resonant inelastic light scattering probe breaking of spin rotational invariance and are used to link this optical emission with collective phases of electrons. A remarkably rapid interplay between emission peak intensities manifests phase competition in the second Landau level.Ultra-clean two dimensional electron systems in the presence of high perpendicular magnetic fields B are a source of unexpected and fascinating quantum many-body physics that arises from the strong electron interactions combined with a reduction in dimensionality. When B is high enough for all electrons to occupy the lowest (N=0) Landau level (LL), the many-electron system forms liquids of the fractional quantum Hall effect (FQHE). When B is such that electrons fill states in higher (N ≥ 2) LL's, electrons form quantum phases referred to as stripe and bubble phases, which lead to transport anisotropy and reentrant integer quantum Hall effect (RIQHE) states [1][2][3]. The unique electron-electron interactions in the N=1 LL result in the presence of RIQHE states and stripe phases in addition to even-and odd-denominator FQHE states [3,4]. FQHE states in the second (N=1) LL exhibit evendenominator states such as the one at ν = 5/2 [5, 6], which is predicted to have non-Abelian excitations [7][8][9][10][11][12][13][14], has recently been studied by NMR [15,16], by light scattering methods [17,18], and in two-subband systems [19]. It has been predicted that the less studied FQHE state at ν = 2 + 1/3 = 7/3 could possess exotic quasiparticles in which composite fermions are dressed by a cloud of neutral excitations [20]. Since FQHE liquids as well as bubble and stripe phases can serve as ground states, the N=1 LL is home to a striking competition between quantum phases [21].The interplay of anisotropic phases with FQHE liquids in the second LL has been studied by introduction of in-plane magnetic fields [3,[22][23][24][25]. These experiments provide evidence that anisotropic smectic-or nematic-like phases with broken full rotational invariance coexist with quantum Hall liquids [26][27][28][29][30]. The large anisotropy induced in the system at the FQHE states at ν = 5/2 and ν = 7/3 by relatively small in-plane magnetic fields [22][23][24] supports interpretations in terms of a new state of electron matter with FQHE states that occur in the environment of a nematic stripe phase [30][31][32].We report optical emission experiments that probe quantum phases that emerge in the second LL of an ultra-clean 2D electron system. The optical recombination is from transitions across conduction to valence band states from electrons that partially populate the N=1 LL. This emission, while much weaker than the one originating in the N=0 LL (...