The boundary conditions for a slightly rarefied gas are derived by the methods of nonequilibrium thermodynamics in the Burnett approximation. It is shown that when the Burnett's terms are taken into account a new type of gas slipping due to a change of the Knudsen stresses, as well as cross mechanico-calorical phenomena are displayed. These Knudsen thermal-stress-slipping and mechanico-calorical effects should be observable experimentally. An additional feature of the Burnett approximation boundary conditions is the existence of connections (in addition to the Onsager relations) between the kinetic coefficients occurring in the boundary conditions. These connections may be deduced also from the Boltzmann equation. They result in a reduction of the calculations of the kinetic coefficients incorporated in the boundary conditions.