Due to the high importance of viscoelastic materials in modern industrial applications, besides the intensive popularity of piezoelectric smart structures, analyzing their thermoelastic response in extreme temperature conditions inevitably becomes very important. Accordingly, this research explores the thermoviscoelastic response of sandwich plates made of a functionally-graded Boltzmann viscoelastic core and two surrounding piezoelectric face-layers subjected to electrothermal load in the platform of three-dimensional elasticity theory. The relaxation modulus of the FG viscoelastic layer across the thickness follows the power law model. the plate’s governing equations are expressed in the Laplace domain to handle mathematical complications corresponding to the sandwich plate with a viscoelastic core. Then, the state-space method, combined with Fourier expansion, is utilized to extract the plate response precisely. Finally, the obtained solution is converted to the time domain using the inverse Laplace technique. Verification of the present formulation is compared with those reported in the published papers. Finally, the influences of plate dimension, temperature gradient, and relaxation time constant on the bending response of the above-mentioned sandwich plate are examined. As an interesting finding, it is revealed that increasing the length-to-thickness ratio leads to a decrease in deflections and an increase in stresses.