Abstract-In this letter we present a wedge-cell method and then compare it with other techniques that can be used to determinate refractive indices of liquid crystalline materials. This simple goniometric technique is of particular significance when used for liquid crystalline materials characterized by high refractive indices, for which refractometric methods are approaching their upper limits. Importantly, the measurement technique proposed here requires a relatively small amount of liquid crystalline material and gives appropriate results for different light sources from the wide spectral range, allowing thus for chromatic dispersion curves (in different temperatures) to be obtained.Liquid crystals (LCs) are unique anisotropic materials with special optical properties. In particular, their refractive indices strongly depend on temperature and molecular orientation, which plays an important role in practical applications of LCs in photonics. Most of LCs are uniaxial and their optical birefringence, defined as a difference between an extraordinary and ordinary refractive index (Δn=n e −n o ), together with their chromatic dispersion, are the most important parameters to be determined in order to ensure proper design, fabrication and functionality of LC-based photonic elements and devices. It is critical thus to deliver and elaborate a convenient and accurate method for refractive index measurements, specifically in a broad spectral range and as a function of temperature [1][2][3][4][5][6][7]. Typically, optical characterization of liquid crystalline materials in terms of chromatic dispersion is performed at room temperature, while the thermal dependence of refractive indices is usually given for one wavelength only (e.g. 589nm which is characteristic for D-sodium-line). Such information is insufficient when needed for proper design and operation of LC-based photonic devices.The experimental setup proposed here, schematically shown in Fig. 1, allows for various monochromatic lasers sources, as well as tunable light source as a monochromator to be applied in order to determine the refractive indices of liquid crystalline materials under tests. A critical issue in the method described here is to place a liquid crystalline material between two glass plates forming a wedge-cell of relatively small angle (of a single degree) and to introduce planar alignment of liquid crystalline molecules on glass substrates. For experimental procedure, the wedge angle has to be known and it can be determined by illuminating an empty cell with a beam perpendicular to one of the glass plates, measuring the distance between the spots coming from the reflection (d 1 on screen A).When a liquid crystal is placed inside the wedge-cell two spots are observed on screen B due to the anisotropy of the LC material. These spots correspond to ordinary and extraodinary rays and are distanced by d 2o and d 2e , respectively, with respect to the initial spot given by the beam passing through the wedge-cell when it was empty. Relatively long distanc...