Today, a lot of attention
is paid to remote controlled opto-electronic
devices. Many of them are commonly used in the society, industry,
and science. Accessories dedicated to the particular utilization are
desired. The point is to find a simple way to obtain smart and functional
appliances. Materials engineering faces such problems and provides
a variety of solutions concerning advanced material design, preparation,
and utilization. Photochromic materials represent one of the already
known materials, which still find other objectives in new fields of
life. In our work, we present two differently constructed photoresponsive
polymers, which give significantly different nonlinear optical (NLO)
response visible as noticeable optical signal modulation. By playing
with diversified laser light energy or its frequency, NLO output characterized
appealing, and individual characteristics (doubled Δ
n
∼0.02 vs 0.04 and entirely different kinetics for
two similar materials and the same laser pumping). Interestingly,
high output signal repeatability and stability were achieved, which
indicate the investigated materials as promising candidates in the
construction of various opto-electronic devices. Additionally, a set
of photoresponsive studies, reflectometry, and theoretical insights
was performed and included in this work.