Magnetic ac susceptibility of randomly arranged crystallites ͑powder sample͒ and well-oriented Fe 8 crystallites has been measured as a function of applied magnetic field, temperature, and frequency. The Fe 8 clusters, made of eight iron ions and with formula ͓͑tacn͒ 6 Fe 8 O 2 ͑OH͒ 12 ͔ 8ϩ , have a ground state Sϭ10. From the magnetization data M (H) with the dc field, H, applied parallel and perpendicular to the easy axis of the aligned sample and Љ(T) data for different frequencies, the anisotropy field H an ϳ5 T and energy barrier U/k B ϭ26.9 K were obtained. Peaks in the curves of Ј(H) were clearly observed at fields H n ϭnH 0 , with nϭ0,Ϯ1 for powder sample where H 0 ϭ2.4 kOe; and nϭ0, Ϯ1, Ϯ2, for an oriented sample where H 0 ϭ2.2 kOe. These peaks appearing at H n ϭnH 0 in the curves of Ј(H) can be well described by the thermally assisted resonant quantum tunneling of magnetization.