A b s t r a c tVirial corrections to the Boltzmann equation for quasiparticles are obtained from non-equilibrium Green's functions. These corrections are expressed in terms of shifts in space and time that characterize non-locality of scattering integrals. The space shifts parallel finite-diameter corrections to collisions of hard spheres. The time shift is identified as the collision delay. All shifts are given by derivatives of the phase shift in a binary collision.
-1 IntroductionThe very basic idea of the Boltzmann equation (BE), to balance the drift of particles with dissipation, is used for the description of transport properties of gases, plasmas and condensed systems like metals or nuclei. In all these fields, the BE allows for a number of improvements which make it possible to describe phenomena beyond the range of validity of the original BE. In these improvements theory of gases differs from theory of condensed systems. Two principal streams of kinetic theory are thus established.In theory of gases, the focus was on so called virial corrections that take into account a finite volume of molecules. The BE includes a contradiction: the scattering cross sections reflect the finite volume of molecules, while the instant and local approximation of scattering events implies the equation of state of an ideal gas. To achieve consistency and extend validity of the BE to moderately dense gases, space non-locality of binary collisions have to be taken into account as it was firstly demonstrated in Enskog's equation [l].In the theory of condensed systems, modifications of the BE are determined by the quantum mechanical statistics. A headway in this field is covered by the Landau concept of quasiparticles [2]. There are three major modifications: the Pauli blocking of scattering channels; underlying quantum mechanical dynamics of collisions; and quasiparticle renormalization of a single-particlelike dispersion relation. With all these deep modifications, the scattering integrals of the BE remain local in space and time. In other words, the Landau theory does not include a quantum mechanical analogy of virial corrections.The aim of this article is to bridge these two streams of the kinetic theory. We follow the work [3] where the way how to derive the quasiparticle kinetic equation with nonlocal and noninstant kinetic equation is presented.
Kinetic equationTo motivate our approach, let u s inspect how the Landau theory exploits information accessible from microscopic theory of binary collisions. Amplitudes of the wave function in individual scattering channels furnishes us with differential cross sections. Phase shifts in the non-dissipative (elastic zereangle) scattering channel provides the quasiparticle renor-