2019
DOI: 10.1021/acs.analchem.9b01730
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Nonresonant Transmission Line Probe for Sensitive Interferometric Electron Spin Resonance Detection

Abstract: Electron spin resonance (ESR) spectroscopy measures paramagnetic free radicals, or electron spins, in a variety of biological, chemical, and physical systems. Detection of diverse paramagnetic species is important in applications ranging from quantum computation to biomedical research. Countless efforts have been made to improve the sensitivity of ESR detection. However, the improvement comes at the cost of experimental accessibility. Thus, most ESR spectrometers are limited to specific sample geometries and c… Show more

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Cited by 8 publications
(11 citation statements)
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“…After decades of development and research, the fault barium (distance algorithm) mainly includes the following categories: impedance method, fault analysis method, traveling wave method, frequency-domain method, and artificial intelligence algorithm [6]. Among them, impedance method and fault analysis method are both short-circuit.…”
Section: Introductionmentioning
confidence: 99%
“…After decades of development and research, the fault barium (distance algorithm) mainly includes the following categories: impedance method, fault analysis method, traveling wave method, frequency-domain method, and artificial intelligence algorithm [6]. Among them, impedance method and fault analysis method are both short-circuit.…”
Section: Introductionmentioning
confidence: 99%
“…An excellent alternative to having to choose between either sensitivity or sample access was proposed recently in the form of a non-resonant transmission linebased interferometric EPR detection [161] scheme. This interferometric design was deployed with a classic bilateral B 0 field, but the interferometric EPR is agnostic of B 0 field generation and could be implemented as the basis of another example of unilateral EPR.…”
Section: Non-resonant Epr With An Interferometric Designmentioning
confidence: 99%
“…The TRMC measurements rely on electric field coupling to the photoactive sample to sense the change in photoconductivity, while the ESR measurements rely on the magnetic field coupling to sense the spin transitions in DPPH. Detection occurs in transmission mode (rather than the reflection mode) with the transmission line structure inserted into the "sample arm" of the microwave interferometer 22 circuit which operates at X-band frequencies (8−12 GHz).…”
Section: ■ Introductionmentioning
confidence: 99%
“…The microwave interferometer is assembled in a Mach-Zehnder configuration 22 which is tuned to null the output in the absence of a transient photoconductivity impedance change. The output of the microwave interferometer is amplified and then demodulated (homodyne) to reveal the transient impedance change.…”
Section: ■ Introductionmentioning
confidence: 99%
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