In this paper we consider a class of systems of two coupled real scalar fields in bidimensional spacetime, with the main motivation of studying classical or linear stability of soliton solutions. Firstly, we present the class of systems and comment on the topological profile of soliton solutions one can find from the first-order equations that solve the equations of motion. After doing that, we follow the standard approach to classical stability to introduce the main steps one needs to obtain the spectra of Schrödinger operators that appear in this class of systems. We consider a specific system, from which we illustrate the general calculations and present some analytical results. We also consider another system, more general, and we present another investigation, that introduces new results and offers a comparison with the former investigations.