In this paper, we consider the upper critical Choquard equation with a local perturbationqγq −2 p 2( p−1) with γq = N 2 − N q and K being some positive constant, we prove (1) Existence and orbital stability of the ground states.(2) Existence, positivity, radial symmetry, exponential decay and orbital instability of the "second class' solutions.This paper generalized and improved parts of the results obtained in [14,15,36,38] to the Schrödinger equation.