Notes- Dicyclopropylglycolic Acid

Zaugg, Harold E.; Springer, N; Michaels, R. J.

doi:10.1021/jo01074a609

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2007

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“…For the synthesis of the title compound, see: Zaug et al (1960). For the crystal structures of some compounds bearing two cyclopropane groups bonded to an O-bonded C atom, see: Yus et al (2005); Febles et al (2004).…”

Section: Related Literaturementioning

confidence: 99%

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2,2-Dicyclopropylglycolic acid

Betz

Klüfers

2007

Acta Crystallogr E Struct Rep Online

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The title compound, C8H12O3, is the parent acid of a tentative ligand whose binding capability toward a metal ion is modified compared with the smaller and more hydrophilic glycolic acid. In the crystal structure, chains of homodromic rings made up of O—H–π and C=O–π co‐operative sequences are lined up along [100]. The homodromic rings are at the centres of tetramers of the title compound. They are 12‐membered and contain two carboxy OH, two alcohol OH and two C=O functions. The rings are connected along the chain direction by the central C—C bond of the acid. The hydrophilic chains are embedded in a lipophilic matrix of hydrocarbon residues.

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Section: Related Literaturementioning

confidence: 99%

“…The title compound was prepared according to standard procedures (Zaug et al, 1960) upon aqueous oxidation of 1,1-dicyclopropyl-prop-2-yne-1-ol. Crystals suitable for X-ray analysis were obtained upon the free evaporation of a solution of the compound in diethylether at room temperature.…”

Section: S2 Experimentalmentioning

confidence: 99%