Notes on the article of V. M. Markochev and E. M. Morozov ?energy relationships in the deformation of a sample with a crack?

Krasovskii, A. Ya.

doi:10.1007/bf01118041

Cited by 3 publications

(4 citation statements)

References 1 publication

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“…A completely different mode of thermal decomposition of polymers can be achieved when a polymer is exposed to pulsed‐IR laser radiation 7–14. This specific thermal decomposition occurs within a T‐jump and is controlled by kinetic rather than thermodynamic polymer degradation.…”

Section: Introductionmentioning

confidence: 99%

IR Laser‐Induced Degradation of Poly(vinyl acetate): Novel Thermal Reactions in Solid Polymers

Kupčı́k

Blazevska-Gilev

Pola

2005

Macromol. Rapid Commun.

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Summary: Pulsed‐IR laser‐induced decomposition of poly(vinyl acetate) (PVAC) differs remarkably from its conventional pyrolysis, which results in the formation of acetic acid and non‐polar carbonaceous residue. In contrast, the products in the former case are (i) vinyl acetate (low energy channel), (ii) products of cleavage in the acetate group, and (iii) an ablatively deposited polar polymeric film containing roughly half of the acetoxy groups initially present.

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Section: Introductionmentioning

confidence: 99%

IR Laser‐Induced Degradation of Poly(vinyl acetate): Novel Thermal Reactions in Solid Polymers

Kupčı́k

Blazevska-Gilev

Pola

2005

Macromol. Rapid Commun.

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“…The pulsed laser ablation − for deposition (PLAD) of thin polymeric films using ultraviolet − and infrared − radiation has been continuously attracting much attention. The UV PLAD involves both photochemical and thermal features, ,, whereas the IR PLAD is a specific thermal process controlled by kinetic rather than thermodynamic polymer degradation.…”

Section: Introductionmentioning

confidence: 99%

Laser Ablative Structural Modification of Poly(ethylene-alt-maleic anhydride)

Pola¹,

Kupčı́k²,

Durani³

et al. 2003

Chem. Mater.

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Pulsed IR laser ablation of poly(ethylene-alt-maleic anhydride) results in the deposition of polymeric films possessing the same ratio of anhydride and -CH 2 -groups and represents a very rare example of laser ablative deposition of polymeric films that are structurally identical to the ablated polymer. This process differs from the conventional thermolysis of poly(ethylene-alt-maleic anhydride) that is controlled by expulsion of CO 2 and CO and yields a nonpolar polymeric residue. The IR laser ablation of poly(ethylene-alt-maleic anhydride) in sodium metasilicate affords deposition of polymeric films containing carboxylate (-CO 2 -) groups. This process is the first example of reactive ablation in which the deposited polymeric film incorporates constituents of two different species exposed to laser radiation.

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“…Laser evaporation/deposition of polymers by using infrared laser radiation has been, however, little studied . This process is achieved through multiphoton resonant absorption of energy-poor infrared photons leading to high vibrational excitation density in the solid .…”

Section: Introductionmentioning

confidence: 99%

“…Successful IR laser ablation/deposition of polymeric films was demonstrated with poly(chlorotrifluoroethylene), poly(tetrafluoroethylene), polysulfone, polycarbonate, and polyimide (all ref a), with poly(fluoroethylene) (ref b), and with polysilanes and polycarbosilanes composed of −(CH 3 ) 2 Si−, −(CH 3 ) 2 Si(CH 3 ) 2 SiCH 2 −, −R(CH 3 )Si−, and −R(CH 3 )Si(CH 3 ) 2 SiCH 2 CH 2 − units where R = methyl, adamanthyl, phenyl, and H (ref c).…”

Section: Introductionmentioning

confidence: 99%

Thermally Stable Polyoxocarbosilane Thin Films by Pulsed IR Laser Ablation of Poly[oxy(tetramethyldisilane-1,2-diyl)]

et al. 2002

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Pulsed IR laser-induced ablation of bulk poly[oxy(tetramethyldisilane-1,2-diyl)], [(CH 3 ) 2 -Si(CH 3 ) 2 SiO] n ,yields thin polyoxocarbosilane films whose polymeric structure consists of a backbone composed of -(CH 3 ) 2 Si(CH 3 ) 2 SiO-and -O(CH 3 ) 2 SiO-units, which is cross-linked via SiSiC 2 O, C 3 SiO, C 2 SiHO, CSiHO 2 , and CSiO 3 moieties. These laser-fabricated hybrides of siloxanes and polysilylenes are insoluble in organic solvents and thermally superior to siloxanes and polysilylenes, which makes them intriguing for applications in thermally exposed devices.

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Notes on the article of V. M. Markochev and E. M. Morozov ?energy relationships in the deformation of a sample with a crack?

Cited by 3 publications

References 1 publication

IR Laser‐Induced Degradation of Poly(vinyl acetate): Novel Thermal Reactions in Solid Polymers

IR Laser‐Induced Degradation of Poly(vinyl acetate): Novel Thermal Reactions in Solid Polymers

Laser Ablative Structural Modification of Poly(ethylene-alt-maleic anhydride)

Thermally Stable Polyoxocarbosilane Thin Films by Pulsed IR Laser Ablation of Poly[oxy(tetramethyldisilane-1,2-diyl)]

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