We establish a geometric interpretation of orientifold Donaldson-Thomas invariants of σ-symmetric quivers with involution. More precisely, we prove that the cohomological orientifold Donaldson-Thomas invariant is isomorphic to the rational Chow group of the moduli space of σ-stable selfdual quiver representations. As an application we prove that the Chow Betti numbers of moduli spaces of stable m-tuples in classical Lie algebras can be computed numerically. We also prove a cohomological wall-crossing formula relating semistable Hall modules for different stabilities.