Novel An Efficient Fluorescent Probe Based on Calix[4]triazacrown-5 With Naphthalimide Group for Co2+, Cd2+ and Dopamine Detection

Sayın, Serkan; Çay, Seydahmet

doi:10.1007/s10895-023-03314-z

Cited by 4 publications

(1 citation statement)

References 59 publications

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“…The highly sensitive and selective measurements of specific analytes can be achieved with appropriate modifications in the calix[4]arene parent moiety. Although there are many sensors for the detection of molecular ions, neutral molecules, and biomolecules consisting of calix[4]arene as their backbone, 31–42 there are few reported methods based on calix[4]arene, and it is still a challenge for synthetic chemists to construct molecular sensors for the detection of pesticides.…”

Section: Introductionmentioning

confidence: 99%

Construction of coumarin-appended calix[4]arene-based fluorescence sensor for the detection of carbofuran in cabbage

Soni,

Verma,

Chaudhari

et al. 2024

Anal. Methods

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Section: Introductionmentioning

confidence: 99%

Construction of coumarin-appended calix[4]arene-based fluorescence sensor for the detection of carbofuran in cabbage

Soni,

Verma,

Chaudhari

et al. 2024

Anal. Methods

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Novel Anthracene‐Appended Calix[4]triazacrown‐5 as an Effective Fluorescence Probe for Co²⁺ and Hazardous Cr₂O₇²⁻ Ions

Sayin

2024

Luminescence

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A new calix[4]triazacrown‐5–derived fluorescence chemosensor (AntUr‐AzClx) at cone conformation was synthesized to afford an effective fluorescent probe, which enables an enhancement in the fluorescence intensity specifically in the presence of Co2+ metal ions as well as a turnoff response for hazardous dichromate anions. 1H‐NMR, 13C‐NMR, ESI‐MS, and elemental analysis techniques were used to characterize the structure of the anthracene‐appended calix[4]triazacrown‐5 (AntUr‐AzClx). The metal ion–binding ability of AntUr‐AzClx was evaluated against Co2+, Ba2+, Ni2+, Pb2+, and Zn2+ ions. On the basis of various metal ion recognition phenomena, AntUr‐AzClx exhibited outstanding selectivity for only the Co2+ ion among other metal ions. Also, the calix[4]triazacrown‐5–derived fluorescence chemosensor showed high sensitivity towards the Co2+ ion with a very low limit of detection (LOD) 0.142 μmol L−1. In addition, anion binding abilities of AntUr‐AzClx against various anions such Cr2O72−, HCO3−, CO32−, NO3−, SO32−, SO42−, N3−, F−, and I− demonstrated that AntUr‐AzClx enables selective and highly sensitive detection of the Cr2O72− anion with an excellent LOD of 4.182 nmol L−1 in DMF/PBS (1/1, v/v; pH: 7.05). Furthermore, the calix[4]triazacrown‐5–derived fluorescence chemosensor displayed a significant sensing behavior to detect the presence of dichromate anions even in real samples.

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Polydiacetylene Liposome-Based Dual-Output Optical Sensor for ppb Level Detection of Dopamine in Solution and Solid Phases

Thakuri,

Banerjee,

Chatterjee

2024

Langmuir

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Dopamine (DA), a neurotransmitter, plays a crucial role in regulating motor functions and emotions and can serve as a marker for several diseases. In this study, we report a highly sensitive polydiacetylenes (PDA)-based dual-output sensor for dopamine detection in both solution and solid phases that was developed by modifying PDA liposomes with boronic acid groups at the termini. This sensor exploits the high affinity between the catechol residue of dopamine and the −B(OH) 2 group of the PDAbased probe (PDA-PhBA) to form boronate ester bonds, causing a stress-induced blue-to-red color change along with a steady increase in fluorescence response at λ max 622 nm. The PDA-PhBA-based sensor displays high sensitivity toward dopamine with low limit of detection of 6.2 ppb in colorimetric analysis and 0.6 ppb in fluorimetric measurements, demonstrating its dual optical output ability. The sensor works well for adrenaline, another catecholamine, with similar efficacy. Its practical applicability was validated by the successful recovery of trace level dopamine in blood serum and real water samples. Additionally, immobilizing PDA-PhBA liposomes in sodium alginate produced PDA beads for the solid-phase detection of dopamine with an limit of detection (LOD) of 59 nM (9.0 ppb) in colorimetric detection using a smartphone for capturing images and ImageJ software for analysis.

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Novel An Efficient Fluorescent Probe Based on Calix[4]triazacrown-5 With Naphthalimide Group for Co2+, Cd2+ and Dopamine Detection

Cited by 4 publications

References 59 publications

Construction of coumarin-appended calix[4]arene-based fluorescence sensor for the detection of carbofuran in cabbage

Construction of coumarin-appended calix[4]arene-based fluorescence sensor for the detection of carbofuran in cabbage

Novel Anthracene‐Appended Calix[4]triazacrown‐5 as an Effective Fluorescence Probe for Co²⁺ and Hazardous Cr₂O₇²⁻ Ions

Polydiacetylene Liposome-Based Dual-Output Optical Sensor for ppb Level Detection of Dopamine in Solution and Solid Phases

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Novel An Efficient Fluorescent Probe Based on Calix[4]triazacrown-5 With Naphthalimide Group for Co2+, Cd2+ and Dopamine Detection

Cited by 4 publications

References 59 publications

Construction of coumarin-appended calix[4]arene-based fluorescence sensor for the detection of carbofuran in cabbage

Construction of coumarin-appended calix[4]arene-based fluorescence sensor for the detection of carbofuran in cabbage

Novel Anthracene‐Appended Calix[4]triazacrown‐5 as an Effective Fluorescence Probe for Co2+ and Hazardous Cr2O72− Ions

Polydiacetylene Liposome-Based Dual-Output Optical Sensor for ppb Level Detection of Dopamine in Solution and Solid Phases

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Novel Anthracene‐Appended Calix[4]triazacrown‐5 as an Effective Fluorescence Probe for Co²⁺ and Hazardous Cr₂O₇²⁻ Ions