2005
DOI: 10.1016/j.jcis.2004.08.034
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Novel and global approach of the complex and interconnected phenomena related to the contact line movement past a solid surface from hydrophobized silica gel

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Cited by 46 publications
(45 citation statements)
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“…edu/). For instance, some modified silica gels, in association with water and aqueous solutions, have been used to build efficient innovative colloidal dampers [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16]. Other systems can work as springs [4,8], as thermal machines in appropriate thermodynamic cycles [1,[4][5], or to convert the mechanical and/or thermal energy into electrical energy [21].…”
mentioning
confidence: 99%
“…edu/). For instance, some modified silica gels, in association with water and aqueous solutions, have been used to build efficient innovative colloidal dampers [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16]. Other systems can work as springs [4,8], as thermal machines in appropriate thermodynamic cycles [1,[4][5], or to convert the mechanical and/or thermal energy into electrical energy [21].…”
mentioning
confidence: 99%
“…In this case, the mechanical work dissipated by the system is not equal to the total heat release, as it was described in [44]. The phenomenon of nonoutflow associated with the change in the internal energy is characteristic of the majority of the studied hydrophobic porous media and liquids, namely, water [7,10,19,20,23,24,[33][34][35]37], aqueous solutions of salts [12,27,28], organic compounds, ethylene glycol [5], alcohol [26], and glycerol [45], as well as systems with the liquid metal [1], Wood's alloy [4], and mercury [61,62].…”
Section: Conditions For the Closed Cyclementioning
confidence: 94%
“…The change of the internal energy ∆E also depends on the length (n) of the grafted n-alkylsilane molecule. It is worth noting that, for water and silica gels, an increase in n from 4 to 18 leads to a increase δσ, a decrease in the nonoutflow and a decrease in the change of the internal energy ∆E [7,8,[16][17][18][19][20], whereas for water and the modified medium, the closed cycle is observed for n = 1 and the complete nonoutflow takes place for n = 8 [32]. An increase in the concentration of the NaCl or CaCl 2 salt in the aqueous solution in specific ranges leads to an increase in the quantity δσ and a decrease in the change of the internal energy ∆E for the Fluka 100 C8 silica gel [25,27,28,32].…”
Section: Conditions For the Closed Cyclementioning
confidence: 99%
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“…So water molecules first fill the pores that have the largest apertures and the smallest contact angles and then fill the smaller pores with larger contact angles and so on till all pores are filled with water under external pressure. The difference between intrusion pressure and extrusion pressure is attributed to contact angle hysteresis, which occurs for a rough surface or a chemical heterogeneous surface [6]. When the contact angle is dynamically measured, one can observe different values of advancing angle θa and receding angle θr (θa>θr) as shown in fig.…”
Section: Working Mechanismmentioning
confidence: 98%