2003
DOI: 10.1016/s0021-9517(02)00069-6
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Novel catalysts for advanced hydroprocessing: transition metal phosphides

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Cited by 739 publications
(579 citation statements)
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“…Nickel phosphide (Ni 2 P) belongs to the class of metal-rich transition metal-main group element compounds (TM compounds), and has recently drawn much attention because of its high activity for hydrodesulfurization reactions [1,2]. Several surface science studies of Ni 2 P single crystals have been conducted in order to elucidate the surface structure of Ni 2 P and shed light on its high activity [3][4][5][6][7][8][9].…”
Section: Introductionmentioning
confidence: 99%
“…Nickel phosphide (Ni 2 P) belongs to the class of metal-rich transition metal-main group element compounds (TM compounds), and has recently drawn much attention because of its high activity for hydrodesulfurization reactions [1,2]. Several surface science studies of Ni 2 P single crystals have been conducted in order to elucidate the surface structure of Ni 2 P and shed light on its high activity [3][4][5][6][7][8][9].…”
Section: Introductionmentioning
confidence: 99%
“…[1][2][3] Another example is the hydrodesulfurization reaction on Ni 2 P / SiO 2 where partially formed Ni-S bond plays an important role in S-C bond scissions during the hydrodesulfurization. 4,5 The characterization of spatial inhomogeneity in heterogeneous catalysts is a key issue in understanding these catalytic reactions.…”
Section: Introductionmentioning
confidence: 99%
“…More recently, transition metal phosphides prepared by temperature-programmed reduction (TPR) were reported to have high catalytic activity for both HDN [6][7][8][9][10][11][12][13][14][15][16][17][18] and HDS [10][11][12][13][14][15][16][17]19,20]. Among these phosphide catalysts, molybdenum phosphides (MoP, MoP/SiO 2 , and MoP/ Al 2 O 3 ) [6][7][8][9]14,15,[17][18][19] received the most attention.…”
Section: Introductionmentioning
confidence: 99%