The three-dimension (3D) flower-like α-Fe 2 O 3 @TiO 2 core-shell nanocrystals with thorhombic, cubic and discal morphologies are synthesized for photocatalytic application. α-Fe 2 O 3 nanocrystals were prepared via Cu 2+ , Zn 2+ and Al 3+ ions-mediated hydrothermal route. The α-Fe 2 O 3 @TiO 2 core-shell nanocrystals are obtained via hydrothermal and annealing process. The shape-dependent photocatalytic activity of these as-obtained α-Fe 2 O 3 @TiO 2 core-shell nanocrystals are measured. The results reveal that the discal α-Fe 2 O 3 @TiO 2 nanocrystals exhibit the best photocatalytic activity than other two core-shell nanocrystals. Because the discal α-Fe 2 O 3 nanocrystals possess more rough surface and surface defects. The fast interfacial charge transfer process and the wide spectral response could be the driving force for the enhanced photocatalytic performance. These core-shell architectures provide a positive example for synthesis of novel composite nanomaterial.