Novel fluorine-containing .beta.-diketone chelating agents

Scribner, William G.; Smith, Brandes H.; Moshier, Ross W.; Sievers, Robert E.

doi:10.1021/jo00830a106

Cited by 18 publications

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“…Important material in the thin film development which is used in optical device 2 , radiopharmaceuticals 3 . β-diketone perform as versatile reactant for different reactions of number of heterocycles 4 pharmacological importance of flavones 5 , luminescence assets of pyrazolic 6 , isoxazolyl 7 , triazolic 8 , pyrimidines 9 . β-diketone is utilized as chelating agent 10 , toxic metal ions adsorbed on different resin 11 , protection from harmful radiation, toxins by cosmetics sunscreen 12 , anti-HIV-1 drug design 13 .…”

Section: Introductionmentioning

confidence: 99%

Synthesis, characterization of Novel β-diketone Ni, Fe, Cr Complexes and study of its Antifungal, Antibacterial, Antioxidant and Anti-Inflammatory Activity.

2021

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Theβ-dike toneis synthesizedvia the named Baker-Venkataraman. In currenttask, β-dike tone ligand mixed with different metal nitrates and form different metal complexes such as Ni(II), Fe(III), Cr(III). Ligand gives tautomerism, this tautomerism process was examined with the help ofFTIR.Because of enol assist as ligand in the metal complexes preparation. The preparedmetal complexearede scribed by various techniques like elemental analysis, FTIR, DTA, TGA, magnetic properties and molar conductivities. Different properties of complexes are studied such as antioxidant, antibacterial, anti-inflammatory and anti fungal properties.

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Section: Introductionmentioning

confidence: 99%

Synthesis, characterization of Novel β-diketone Ni, Fe, Cr Complexes and study of its Antifungal, Antibacterial, Antioxidant and Anti-Inflammatory Activity.

2021

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“…(βd) acts as multipurpose precursor for many reactions of numerous heterocycles 4 for example flavones 5 , isoxazolyl, pyrazolic 6 , pyrimidines, triazolic 7 . (βd) is used in metal withdrawal by chelating agent 8 , textile 9 , resin 10 , sunscreen cosmetics 11 , HIV-1 avoidance 12 . Ln (III) (βd) shows luminescent property 13 .…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Characterization, Antibacterial, Antifungal, Antioxidant and Anti-Inflammatory Actions of Novel β-Diketone Complex

Bibave

Athare

2019

Orient. J. Chem

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β-diketone (βd) is prepared using the name reaction Baker-Venkataraman transformation reaction. In this present work, ester (c’) was prepared when 1-(2-Hydroxy-5-methyl-phenyl)-ethanone (a’) was treated with 4-Propoxy-benzoic acid (b’) at 0 °C to 10 °C. (c’) on Baker-Venkataraman transformation to give β-diketone ligand (L’) named as 1-(2-Hydroxy-5-methyl-phenyl)-3-(4-propoxy-phenyl)-propane-1,3-dione. Bidentate ligand (L’) treated with Cu (II) nitrate gives Cu (II) complex (CuL’). (L’) shows tautomerism, this tautomerism phenomenon was studied using FTIR and NMR. Because of enol serve as ligand (L’) in the synthesis of (CuL’). The prepared (L’) can be characterized by HR-MS, elemental analysis, 1H, 13C, DEPT, D2O exchange, FTIR. The antibacterial, antifungal, antioxidant, anti-inflammatory property of (CuL’) is studied.

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“…1), 15 which is soluble in FC-72. 16 Extraction profiles of the FC-72 system were studied and compared with that of organic solvent systems.…”

Section: Introductionmentioning

confidence: 99%

Metal Extraction from Water and Organic Solvents into Fluorous Solvents by Fluorinated β-Diketone and Its Application to the Colorimetric Analysis of Metal Ions

et al. 2009

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Novel fluorine-containing .beta.-diketone chelating agents

Cited by 18 publications

References 0 publications

Synthesis, characterization of Novel β-diketone Ni, Fe, Cr Complexes and study of its Antifungal, Antibacterial, Antioxidant and Anti-Inflammatory Activity.

Synthesis, characterization of Novel β-diketone Ni, Fe, Cr Complexes and study of its Antifungal, Antibacterial, Antioxidant and Anti-Inflammatory Activity.

Synthesis, Characterization, Antibacterial, Antifungal, Antioxidant and Anti-Inflammatory Actions of Novel β-Diketone Complex

Metal Extraction from Water and Organic Solvents into Fluorous Solvents by Fluorinated β-Diketone and Its Application to the Colorimetric Analysis of Metal Ions

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