Novel metal-organic and supramolecular 3D frameworks constructed from flexible biphenyl-2,5,3′-tricarboxylate blocks: Synthesis, structural features and properties

You, Ao; Yu, Li; Zhang, Zemin; Zou, Xun-Zhong; Gu, Jin‐Zhong; Kirillov, Alexander M.; Chen, Jinwei; Chen, Yun-Bo

doi:10.1016/j.molstruc.2017.05.075

Cited by 5 publications

(3 citation statements)

References 40 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Within the layer, Zn atoms deviate from their mean plane by 0.55 Å ( Figure S7). Similar to compound 1, the dicarboxylate ligand in complex 2 adopts a (µ-O) 2 -coordination mode, revealing pairs of short (1.93, 1.98 Å) and long (2.61, 3.29 Å) Zn···O distances. According to the analysis of the d norm map on the Hirshfeld surface, the O14 atom shows weak interaction with the Zn, as well as with the H, atom of the triazole unit with corresponding Zn···O and H···O distances of 2.61 and 2.53 Å (Figure S5).…”

Section: Synthesis Of Coordination Polymersmentioning

confidence: 93%

“…In contrast to atom O22, atom O12 reveals contact with the H of the neighboring triazole unit, with a corresponding distance of 2.25 Å (Figure S4b). {Zn(tdc)} chains are linked by (µ-N) 2 -coordinating btrm ligands to form corrugated layers arranged along the ac plane (Figure 2b). Within the layer, Zn atoms deviate from their mean plane significantly by 3.54 Å ( Figure S6).…”

Section: Synthesis Of Coordination Polymersmentioning

confidence: 99%

“…Coordination polymers and metal-organic frameworks attract the unceasing attention of researchers due to their wide range of potential applications [1][2][3][4][5][6]. One of the universal approaches to the construction of metal-organic frameworks uses a combination of metal ions with aromatic dior polycarboxylate donors and rigid or flexible N-donor bitopic ligands [7,8].…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane

et al. 2017

View full text Add to dashboard Cite

Abstract:Two new two-dimensional zinc(II) coordination polymers containing 2,5-thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis (1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed.

show abstract

Section: Synthesis Of Coordination Polymersmentioning

confidence: 93%

Section: Synthesis Of Coordination Polymersmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane

et al. 2017

View full text Add to dashboard Cite

show abstract

3D-Supramolecular Coordination Polymer Nanoparticles Based on Cd(II) and Mixed Ligands: Single Crystal X-Ray Structure, Luminescence and Photocatalytic Properties

Etaiw

Marie

2017

J Inorg Organomet Polym

View full text Add to dashboard Cite

Construction and Properties of Ag-I Polymeric Clusters Attach with Nitrogen Heterocyclic Transition Metal Moiety

Liu

Bai

et al. 2022

J Inorg Organomet Polym

View full text Add to dashboard Cite

Two silver cluster compounds {[Co(1,10′-phen) 3 ] 2 [Ag 8 I 12 ]} (1) and { [Co(2, 3 ] [Ag 10 I 11 ] (OH) 3DMF 2H 2 O} (2) (1,10′-phen=1,10′-phenanthroline, 2, 2′-bipy=2,2′-bipyridine) were designed and synthesized by solvent evaporation method. The two silver cluster compounds were characterized by elemental analysis, infrared spectroscopy, ultraviolet spectroscopy, thermogravimetric analysis and X-ray powder diffraction. The crystal structures of compounds 1 and 2 were determined by X-ray crystallography diffraction.Through the electrostatic interaction between the metallic Ag cluster moiety and the metallic Co cluster moiety, form stable interlaced layered super molecular structures. In order to explore functional properties, the catalytic reduction of p-nitrophenol and electrochemical behavior of compounds 1 and 2 were explored. The results show that compounds 1 and 2 can e ciently catalyze the reduction of pnitrophenol in the aqueous solution, and the reduction and removal rate can reach more than 90%. Highlights ▪Synthesis of compounds 1 and 2 characterized by single crystal X-ray crystallography in detail.▪1 and 2 through the electrostatic interaction between the metallic Ag cluster moiety and the metallic Co cluster moiety, formed stable interlaced layered super molecular structures.▪1 and 2 can e ciently catalyze the reduction of p-nitrophenol.

show abstract

Novel metal-organic and supramolecular 3D frameworks constructed from flexible biphenyl-2,5,3′-tricarboxylate blocks: Synthesis, structural features and properties

Cited by 5 publications

References 40 publications

Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane

Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane

3D-Supramolecular Coordination Polymer Nanoparticles Based on Cd(II) and Mixed Ligands: Single Crystal X-Ray Structure, Luminescence and Photocatalytic Properties

Construction and Properties of Ag-I Polymeric Clusters Attach with Nitrogen Heterocyclic Transition Metal Moiety

Contact Info

Product

Resources

About