“…Core‐shell micro/nanofibers, double‐compartment materials with advantages of both core and shell components at the same time, 1–4 are a new type of functional fibers which are widely used in battery field, 5 gas sensor, 6,7 photocatalysis, 8,9 biomedical field, 10,11 and flexible electronics, 12,13 and drug delivery 14–17 . There are several methods to produce the core‐shell fibers such as single needle through phase separation, 18,19 emulsion electrospinning, 20,21 template method, 22,23 coaxial electrospinning, 24,25 tri‐axial and modified tri‐axial electrospinning 26,27 .…”