2009
DOI: 10.1002/zaac.200900074
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Novel Octahedral Bis[2‐(1‐aziridinyl)ethanol‐κ2N,O] Complexes of Cobalt(II)

Abstract: The synthesis and molecular structure of trans‐{bis[(acetato‐κO)‐(2‐(1‐aziridinyl)ethanol‐κ2N,O)]}cobalt(II) (4) and cis‐{bis[chlorido‐(2‐(1‐aziridinyl)ethanol‐κ2N,O)]}cobalt(II) (5) is reported. Both neutral chelate complexes are prepared from the corresponding CoII salt [CoX2; X = OAc (1), Cl (2)] and 2‐(1‐aziridinyl)ethanol (azolH, 3) in dry dichloromethane. A third, ionic complex, cis‐{bis[aqua‐(2‐(1‐aziridinyl)ethanol‐κ2N,O)]}cobalt(II) diacetate (6) is formed from 4 in the presence of water and could be … Show more

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