This
study presents the synthesis of orange–red emitting
Sr9Al6O18:Pr3+ nanophosphors
(SAO:Pr3+ NPs) through the solution combustion process.
Photoluminescence (PL) spectra revealed concentration quenching at
5 mol % with a critical distance of R
C = 21.5 Å, indicating that electric multipolar interactions
are responsible for the nonradiative energy transfer in the SAO lattice.
Dexter’s theory confirmed the quadruple–quadruple interaction
as the mechanism behind the quenching. The optimized SAO:5Pr3+ NPs exhibited exceptional properties, including high color purity
(CP = 94.2%), cost-effectiveness, eco-friendliness, scalability, and
photostability. A fluorescence-based technique was developed using
powder dusting to apply latent fingerprint (LFP) visualization and
preservation. This method demonstrated high sensitivity, contrast,
and no background interference, enabling the detection of LFPs over
extended periods. Furthermore, lip prints (LPs), known for their sex
differences and stability, have been effectively utilized for reliable
and efficient forensic investigations. An unclonable invisible security
ink was developed to combat counterfeiting, exhibiting high stability
against UV light, aging, and physical abrasion. Mathematical models
were employed for various fingerprint image processing tasks, including
segmentation, normalization, ridge orientation estimation, ridge frequency
estimation, Gabor filtering, binarization, thinning, and minutiae
extraction. These algorithms were implemented by using a Python-based
environment, resulting in enhanced fingerprints that displayed level
I–II features. These findings underscore the potential applications
of SAO:Pr3+ NPs in advanced forensic science and data security.
This study offers insights into the synthesis, characterization, and
application of SAO:Pr3+ NPs, highlighting their suitability
for advanced forensic investigations, data security, and anticounterfeiting
measures.