Novel perylene‐containing polymers

Quante, Heribert; Schlichting, P.; Rohr, U.; Geerts, Yves; Müllen, Kläus

doi:10.1002/macp.1996.021971205

Cited by 84 publications

(51 citation statements)

References 23 publications

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“…The synthetic procedures are explained in the Supporting Information. [24] 1 H NMR spectra were measured on a Bruker DMX 600 spectrometer. IR spectra were obtained using a Perkin Elmer ATR FTIR spectrometer.…”

Section: Methodsmentioning

confidence: 99%

Visible‐Light‐Harvesting Organogel Composed of Cholesterol‐Based Perylene Derivatives

2004

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Section: Methodsmentioning

confidence: 99%

Visible‐Light‐Harvesting Organogel Composed of Cholesterol‐Based Perylene Derivatives

2004

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“…Both fullerenes and PTCDI-based species are an attractive target in forming multi-component acceptor-donor systems due to their extensive redox chemistry and photochemical properties. [4,[8][9][10][11][12][13][14] Fullerene absorbs light in the UV/Vis range [2] and PTCDI strongly absorbs light in the Vis/near IR range, [15,16] and both possess excellent electron-acceptor characteristics [17][18][19] and have been identified as candidates for the development of photovoltaic devices. [20][21][22] For such applications it is imperative that the electronic/redox and optical properties of the molecular species are fully understood.…”

Section: Introductionmentioning

confidence: 99%

Multi‐Electron‐Acceptor Dyad and Triad Systems Based on Perylene Bisimides and Fullerenes

Chamberlain

Davies

Khlobystov

et al. 2011

Chemistry A European J

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Fullerene (C(60)) and 3,4,9,10-perylene tetracarboxylic diimide (PTDCI) were used as building blocks for an electron acceptor dyad (C(60)-PTCDI) and triad (C(60)-PTCDI-C(60)). As the first reduction potentials for C(60) and PTCDI are very close, simultaneous introduction of two or three electrons is possible into the dyad and triad, respectively. Further stepwise electrochemical reduction leads to formation of a series of well-defined anionic species in which electrons associated with the fullerene or the PTDCI components of the molecule can be clearly distinguished. In total, up to four electrons can be reversibly injected into the dyad C(60)-PTCDI and up to six into the triad C(60)-PTCDI-C(60) system. The optical absorption properties in the UV/Vis range are also crucially defined by the distribution of electrons between the acceptor parts, as the injection/removal of electrons causes drastic colour changes in the dyad and the triad systems.

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“…One of the principal derivatives of perylene is perylene-3,4:9,10-tetracarboxylic dianhydride (PTCA) [4][5][6] (Fig. 1b) which can be further modified by introduction of substituents into the bay region at positions 1, 6, 7 and 12.…”

Section: Introductionmentioning

confidence: 99%

Interpreting the near-infrared reflectance of a series of perylene pigments

2013

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This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. and combination modes of fundamental IR vibrations appear to be more important in explaining the observed variations in NIR reflectance/absorbance. Aromatic groups lead to a small number of intense NIR bands, while alkyl groups generally lead to a greater number of less intense NIR bands. However, neighbouring group effects and/or a molecular dipole moment can substantially alter the intensity of these bands.

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Novel perylene‐containing polymers

Cited by 84 publications

References 23 publications

Visible‐Light‐Harvesting Organogel Composed of Cholesterol‐Based Perylene Derivatives

Visible‐Light‐Harvesting Organogel Composed of Cholesterol‐Based Perylene Derivatives

Multi‐Electron‐Acceptor Dyad and Triad Systems Based on Perylene Bisimides and Fullerenes

Interpreting the near-infrared reflectance of a series of perylene pigments

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