1997
DOI: 10.1016/s0032-3861(96)00907-x
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Novel photo-crosslinkable flame retardant polyvanillylidene arylphosphate esters

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Cited by 26 publications
(18 citation statements)
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“…Kricheldorf reported the thermotropic liquid crystalline poly(arylphosphate ester)s for the use of high performance fibers and observed that the T g of the polymers decreases with increase in the phosphorus content [21]. In our earlier studies, we have demonstrated that the introduction of phosphate group into the polymer backbone improved their solubility due to its polarity and high char yield [22][23][24][25][26]. The literature survey reveals that the investigations on the synthesis of liquid crystalline and photocrosslinkable polymers (LCPCPs) were scarce [18].…”
Section: Introductionmentioning
confidence: 96%
“…Kricheldorf reported the thermotropic liquid crystalline poly(arylphosphate ester)s for the use of high performance fibers and observed that the T g of the polymers decreases with increase in the phosphorus content [21]. In our earlier studies, we have demonstrated that the introduction of phosphate group into the polymer backbone improved their solubility due to its polarity and high char yield [22][23][24][25][26]. The literature survey reveals that the investigations on the synthesis of liquid crystalline and photocrosslinkable polymers (LCPCPs) were scarce [18].…”
Section: Introductionmentioning
confidence: 96%
“…The mostly reported intumescent flame retardants (IFRs) are the phosphorus-nitrogen containing compounds, which are considered as the promising candidate for replacing halogen containing ones due to their high efficiency and have not been proved to create environmental problems so far. However, these intumescent additives are somewhat volatile and susceptible to migration to the surface during the high temperature processing due to their low molecular weight, and consequently decreases the flame retardancy efficiency [2,3]. To synthesize high molecular weight, namely oligomeric or polymeric IFRs, provides a good strategy to solve the above problems, and previous work in our laboratory showed that this strategy was very successful [4].…”
Section: Introductionmentioning
confidence: 99%
“…[21][22][23][24] N-arylphosphoramidic dichlorides (APD) were prepared from phosphorus oxychloride and respective anilines by adopting the similar reported procedure.…”
Section: Monomersmentioning
confidence: 99%