Novel photoelectric material of perovskite-like (CH3)3SPbI3 nanorod arrays with high stability

Hu, Ruiyuan; Ge, Chuangye; Chu, Liang; Feng, Yifei; Xiao, Shanshan; Ma, Yuhui; Liu, Wei; Li, Xing’ao; Nazeeruddin, Mohammad Khaja

doi:10.1016/j.jechem.2020.12.003

Cited by 26 publications

(24 citation statements)

References 44 publications

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“…In order to study the crystal phase of Me 3 SPbI 3 , we prepared a needle‐like 1D perovskite single crystal (SCs) by following the antisolvent method as reported in our previous work. [ 37 ] The well‐defined diffraction peaks (Figure 1f) suggested a good crystallinity of the obtained Me 3 SPbI 3 nanoarrays, which can be indexed as the hexagonal crystal structure with space group of P6 3mc (No.186) and lattice constants a = b = 9.615 Å, c = 7.950 Å, a = b = 90°, c = 120°. As shown in Figure 1g,h, the face‐shared [PbI 6 ] 4− octahedral form 1D chains along the c axis while the Me 3 S + cations occupy the interstitial sites between [PbI 6 ] 4− in the 1D chains, which are similar to the yellow and thermo‐dynamically stable δ‐FAPbI 3 phase.…”

Section: Resultsmentioning

confidence: 98%

“…[9] However, low efficiency of Me 3 SPbI 3 based solar cell could be attributed to the rough and porous nature of the perovskite film and the relatively narrow absorption range up to around 530 nm compared with other typical 3D perovskite such as MAPbI 3 or FAPbI 3. [32,37] It was a challenge for the preparation of an uniform and homogeneous film due to the large tolerance factor in1D crystal structures [34,37] obtained via two-step solution process. Due to the poor solubility of Me 3 SI in the common solvents, such as DMF, DMSO, or γ-butyrolactone, the surface coverage of perovskite film is poor which results in lower PCE through one-step solution process method.…”

Section: Resultsmentioning

confidence: 99%

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Mixed Dimensional Perovskites Heterostructure for Highly Efficient and Stable Perovskite Solar Cells

Singh

et al. 2021

Solar RRL

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Organic-inorganic hybrid perovskite solar cells (PSCs) have attracted tremendous attention due to their unique optoelectronic properties, power conversion efficiency (PCE), cost-effectiveness, and solution processability. [1][2][3][4][5] Within a few years, the PCE of 3D (3D) perovskite materials based PSCs has rapidly soared from 3.8% to 25.8%, which is comparable with that of the state-of-art monocrystalline silicon solar cells. [6][7][8] However, because of their intrinsic structural characteristics, 3D perovskites still suffer from poor stability in ambient conditions, when exposed to UV light, moisture, heat, and electric field, which limits the commercialization potential of the PSCs. [9][10][11][12][13] To address the longterm stability issue, 1D perovskites are emerging as ideal alternatives due to their structural diversity, tunable optical properties, and superior environmental stability. [14][15][16] From the molecular level, the 1D perovskites, are different from the morphological 1D nanowires, nanofibers, and nanorods. [17] Typically, the [PbX 6 ] 4À octahedral surrounded by organic cations are corner-sharing, edge-sharing, or face-sharing to form a 1D perovskites chain. [18,19] 1D perovskite show superb stability by taking the advantage of the improvement of the skeleton strength attribute to the "shoulder to shoulder" arrangement of [PbX 6 ] 4À and the protection of organic cations. [20] By incorporating large organic cations into the 3D perovskite precursor or post-

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Section: Resultsmentioning

confidence: 98%

Section: Resultsmentioning

confidence: 99%

Mixed Dimensional Perovskites Heterostructure for Highly Efficient and Stable Perovskite Solar Cells

Singh

et al. 2021

Solar RRL

Self Cite

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“…Crystal growth in precursors can be controlled by methods such as external doping, low-temperature growth, and antisolvent environment. [92][93][94][95][96][97][98][99][100][101] For instance, Zhu et al proved that potassium ions can assist the growth of (C 4 H 9 NH 3 ) 2 PbBr 4 into nanobelts. [98] For 2D perovskites, if anisotropic growth is further suppressed by certain ligands, the crystal will avoid growing into plates, but instead grows into wires (Figure 4c).…”

Section: Slow-crystallization Growthmentioning

confidence: 99%

“…For instance, Hu et al prepared a novel (CH 3 ) 3 SI powder to fabricate a vertical nanorod array for solar cells (Figure 10i). [97] The fabricated film had a bandgap of 2.32 eV. The large bandgap created a low PCE of 2.07%.…”

Section: Solar Cellsmentioning

confidence: 99%

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Metal Halide Perovskite Nano/Microwires

Wang

Cao

2021

Small Structures

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Inorganic Halide Perovskite Electromagnetic Wave Absorption System with Ultra‐Wide Absorption Bandwidth and High Thermal‐Stability

Zhang

Xiong

Yao

et al. 2022

Adv Elect Materials

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Halogen perovskite, a novel semiconductor material that has gained momentum in the energy sector, has also emerged in the field of electromagnetic wave (EMW) protection. Inorganic halogen perovskites are expected to perform well owing to their excellent stability and dielectric properties. In this study, a CsPbBr3/Carbon nanotubes (CNTs) composite is designed using a convenient antisolvent method. In addition to an ultrawide absorption bandwidth (5.56 GHz) and ultrahigh absorption strength (|Reflection loss| = 51.74 dB), the composite shows excellent thermal stability and environmental tolerance. In an air environment, its EMW‐absorbing performance can be maintained at a high level at a temperature below 400 °C. CNTs build an efficient conductive network between CsPbBr3 to enhance the conduction loss of the composite, while it brings more defects and vacancies to the surface of CsPbBr3 to form electrical polarization centers which improving the polarization loss of the composite. This is the first study of the application of inorganic halogen perovskites in the field of EMW absorption. The excellent EMW‐absorbing performance and stability of CsPbBr3/CNTs demonstrate the great potential of inorganic halogen perovskites in the field of EMW absorption and provide a valuable reference and feasible strategy for regulating and controlling the EMW‐absorbing performance of perovskite materials.

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Novel photoelectric material of perovskite-like (CH3)3SPbI3 nanorod arrays with high stability

Cited by 26 publications

References 44 publications

Mixed Dimensional Perovskites Heterostructure for Highly Efficient and Stable Perovskite Solar Cells

Mixed Dimensional Perovskites Heterostructure for Highly Efficient and Stable Perovskite Solar Cells

Metal Halide Perovskite Nano/Microwires

Inorganic Halide Perovskite Electromagnetic Wave Absorption System with Ultra‐Wide Absorption Bandwidth and High Thermal‐Stability

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