Novel Poly Deep Eutectic Solvents Based Supported Liquid Membranes for CO2 Capture

Diffusivities and solubilities of carbon dioxide in deep eutectic solvents

“…Saeed et al [18] determined the CO 2 diffusivity in three betaine-based DESs using the time lag method. Ishaq et al [19] measured CO 2 permeabilities through poly DESs supported membranes without reporting gas diffusivities in the DESs. They concluded that DESs should be developed with a low viscosity ensuring a fast absorption rate [20].…”

CO2 Separation Using Supported Deep Eutectic Liquid Membranes Based on 1,2-propanediol

“…They are therefore between for the earlier reported SLMs using different commercial polymeric supports based on DESs consisting of choline chloride and alkanoamines or acids and SLMs based on ILs containing acetic anion. 13,23,25,55 According to the literature, this may be due to many reasons, including differences in the viscosity of solvents and the porosity of solid materials in SLM. 13,55 Selectivity of Studied Membranes.…”

“…They found that among studied membranes, the SLMs containing DES based on monoethanolamine showed excellent selectivity of CO 2 equal to 70.47 and 78.86 for CO 2 /CH 4 and CO 2 /N 2 , respectively. 13,22,23 Saeed et al also examined supported liquid membrane based on PVDF, but in their research, they used DESs composed of betaine and urea/ glycerol/ethylene glycol or DESs consisting of choline chloride and tartaric acid/malic acid/oxalic acid or DES based on potassium carbonate. 24−26 The authors showed that the separation factor CO 2 /CH 4 for the studied SLMs was up to 60.…”

Neoteric deep eutectic solvents: history, recent developments, and catalytic applications

“…Real-time FT-IR spectroscopy studies on the photopolymerization of DEMs indicate that the mixtures formed from MAA and tetrabutylammonium fluoroborate show significant lower initial photopolymerization rate in comparison with other investigated DEMs, which polymerize with similar rates. 48 In general, PODESs are alternatives to ILs, successfully applied in nanotechnology, 49 gas separation, 50 and catalysis 51…”